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Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres

Zhu, Kairuo, Chen, Changlun, Xu, Huan, Gao, Yang, Tan, Xiaoli, Alsaedi, Ahmed, Hayat, Tasawar·2017·ACS Sustainable Chemistry & Engineering

Abstract

A well-defined core-double-shell structured magnetic polydopamine@zeolitic idazolate frameworks-8 (MP@ZIF-8) hydrid microsphere consisting of the core of magnetic Fe 3 O 4 nanoparticles, the inner shell of a polydopamine layer, and the outer shell of a porous ZIF-8 nanocrystal was prepared through a facile and green approach to achieve synergistic reduction and adsorptive removal of Cr(VI). The microsphere property was characterized methodically. The batch adsorption experiments showed that the MP@ZIF-8 exhibited high efficiency in the Cr(VI) removal from aqueous solutions, affording Cr(VI) removal capacity of 136.56 mg g –1, surpassing pristine MP (92.27 mg g –1 ). The pseudo-second-order model fitted the Cr(VI) removal kinetics well. Cr(VI) removal on the MP@ZIF-8 relied highly on pH values. More significantly, with the reduction of nitrogen atom group on ZIF-8 and PDA, Cr(VI) was easily converted into low toxicity Cr(III) and then immobilized on the MP@ZIF-8. Thus, the hybrid microspheres provided excellent adsorptive activity in treating Cr-contaminated wastewater.

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Metadata

Authors
Zhu, K., Chen, C., Xu, H., Gao, Y., Tan, X., Alsaedi, A., & Hayat, T.
Venue
ACS Sustainable Chemistry & Engineering
Published
2017-07-12
Volume
5
Issue
8
Pages
6795-6802
ISSN
2168-0485 (ISSN-L)
OpenAlex
W2725404622
Cited by
263
References
43
FWCI
15.05
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres. https://app.cochat.ai/papers/10.1021/acssuschemeng.7b01036
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Zhu, K., Chen, C., Xu, H., Gao, Y., Tan, X., Alsaedi, A., & Hayat, T. (2017). Cr(VI) Reduction and Immobilization by Core-Double-Shell Structured Magnetic Polydopamine@Zeolitic Idazolate Frameworks-8 Microspheres. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.7b01036

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