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Alkali Metal-Assisted Synthesis of Graphite Carbon Nitride with Tunable Band-Gap for Enhanced Visible-Light-Driven Photocatalytic Performance
Abstract
The development of high-performance semiconductor photocatalysts using solar energy has become a hot topic, which is crucial for a sustainable future. However, construction of a nontoxic and efficient catalyst still remains an enormous challenge. Here, we uncover a simple hydrothermal recalcination method to prepare a novel potassium (K)-doped porous ultrathin g-C 3 N 4 (denoted as KMCN) photocatalyst with efficient catalytic performance, eco-friendly characteristics, and excellent stability. The obtained KMCN nanosheets were applied to the photodegradation of tetracycline (TC) under different reaction condition to simulate practical wastewater treatment. It was found, that the porous structure and K + addition of g-C 3 N 4 enhanced the pore size and specific surface area, and they increased the photoabsorption region and activity sites. The optical properties of KMCN nanosheets were systematically characterized by PL, UV-DRS, etc. The results revealed that the KMCN(0.05) sample possessed a narrowed band gap, lower recombination of photogenerated charges, and higher electron and hole transfer efficiency. Benefiting from these advantages, KMCN(0.05) photocatalysts demonstrated excellent photocatalytic performance for TC degradation (85.13%), which was approximately a 2.88-fold and 1.40-fold increase compared to bare g-C 3 N 4 (29.60%) and porous ultrathin g-C 3 N 4 (60.84%), respectively. These results suggest a reasonable way for the design of economic and high-efficiency photocatalysis.
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Cites
Application of biochar for the removal of pollutants from aqueous solutions
Tan, X., Liu, Y., Zeng, G., Wang, X., Hu, X., Gu, Y., & Yang, Z. (2015) · Chemosphere · doi:10.1016/j.chemosphere.2014.12.058 · Cited by 2,081
Self-citationGong, J.-L., Wang, B., Zeng, G.-M., Yang, C.-P., Niu, C.-G., Niu, Q.-Y., Zhou, W.-J., & Liang, Y. (2009) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2008.09.072 · Cited by 1,057
Self-citationYang, Y., Zeng, Z., Zhang, C., Huang, D., Zeng, G., Xiao, R., Lai, C., Zhou, C., Guo, H., Xue, W., et al. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2018.05.093 · Cited by 691
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Cited by
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Self-citationYang, Y., Li, X., Zhou, C., Xiong, W., Zeng, G., Huang, D., Zhang, C., Wang, W., Song, B., Tang, X., et al. (2020) · Water Research · doi:10.1016/j.watres.2020.116200 · Cited by 518
Self-citationYang, Y., Zeng, G., Huang, D., Zhang, C., He, D., Zhou, C., Wang, W., Xiong, W., Li, X., Li, B., et al. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118970 · Cited by 412
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Metadata
- Authors
- Wang, W., Xu, P., Chen, M., Zeng, G., Zhang, C., Zhou, C., Yang, Y., Huang, D., Lai, C., Cheng, M., Hu, L., Xiong, W., Guo, H., & Zhou, M.
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-10-07
- Volume
- 6
- Issue
- 11
- Pages
- 15503-15516
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2895257214
- Cited by
- 226
- References
- 3
- FWCI
- 7.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, W., Xu, P., Chen, M., Zeng, G., Zhang, C., Zhou, C., Yang, Y., Huang, D., Lai, C., Cheng, M., Hu, L., Xiong, W., Guo, H., & Zhou, M. (2018). Alkali Metal-Assisted Synthesis of Graphite Carbon Nitride with Tunable Band-Gap for Enhanced Visible-Light-Driven Photocatalytic Performance. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.8b03965
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