The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Influence of Cross-linkers on the Cohesive and Adhesive Self-Healing Ability of Polysulfide-Based Thermosets
Abstract
Synthetic systems with intrinsic self-repairing or self-healing abilities have emerged during the past decade. In this work, the influence of the cross-linker and chain rigidity on the healing ability of thermoset rubbers containing disulfide bonds have been investigated. The produced materials exhibit adhesive and cohesive self-healing properties. The recovery of these two functionalities upon the thermally triggered healing events has shown to be highly dependent on the network cross-link density and chain rigidity. As a result, depending on the rubber thermoset intrinsic physical properties, the thermal mending leading to full cohesive recovery can be achieved in 20-300 min at a modest healing temperature of 65 °C. The adhesive strength ranges from 0.2 to 0.5 MPa and is fully recovered even after multiple failure events.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
A self-healing thermosetting composite material
Hayes, S. A., Jones, F. R., Marshiya, K., & Zhang, W. (2007) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2006.06.008 · Cited by 293
Cited by
Advances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
3D Printing of Highly Stretchable, Shape-Memory, and Self-Healing Elastomer toward Novel 4D Printing
Kuang, X., Chen, K., Dunn, C. K., Wu, J., Li, V. C. F., & Qi, H. J. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b18265 · Cited by 523
Malleable and Recyclable Thermosets: The Next Generation of Plastics
Jin, Y., Lei, Z., Taynton, P., Huang, S., & Zhang, W. (2019) · Matter · doi:10.1016/j.matt.2019.09.004 · Cited by 359
Deng, X.-Y., Xie, H., Du, L., Fan, C.-J., Cheng, C.-Y., Yang, K.-K., & Wang, Y.-Z. (2019) · Science China Materials · doi:10.1007/s40843-018-9318-7 · Cited by 87
Metadata
- Authors
- Lafont, U., van Zeijl, H., & van der Zwaag, S.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-25
- Volume
- 4
- Issue
- 11
- Pages
- 6280-6288
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2316589947
- Cited by
- 260
- References
- 2
- FWCI
- 10.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Influence of Cross-linkers on the Cohesive and Adhesive Self-Healing Ability of Polysulfide-Based Thermosets. https://app.cochat.ai/papers/10.1021/am301879z
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- Lafont, U., van Zeijl, H., & van der Zwaag, S. (2012). Influence of Cross-linkers on the Cohesive and Adhesive Self-Healing Ability of Polysulfide-Based Thermosets. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am301879z
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