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Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+

Zheng, Min, Tan, Huaqiao, Xie, Zhigang, Zhang, Ligong, Jing, Xiabin, Sun, Zaicheng·2013·ACS Applied Materials & Interfaces

Abstract

Iron is one of the most important elements in the metabolic process for all living system. However, both its deficiency and excess from normal permissible limits can induce serious disorders. We synthesized a europium-based metal-organic framework (Eu-MOF), EuL(3) (L = 4'-(4-carboxyphenyl)-2,2': 6',2″-terpyridine), under hydrothermal conditions, and used it as a solid luminescence sensor for Fe(3+) ions. The robust EuL(3) shows fast response (∼ 1 min) and high sensitivity (Stern-Volmer constant K(SV) = 4.1 × 10(3) L/mol) for Fe(3+) ions in aqueous solution or biological systems due to the existence of chelating terpyridine and open channels. The simple and portable test paper based on the EuL(3) fluorescent sensor system provides a convenient and reliable detection of Fe(3+) in every day applications. This pioneering work contributes to extend the potential application of Ln-MOFs to the biological and environmental areas.

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Metadata

Authors
Zheng, M., Tan, H., Xie, Z., Zhang, L., Jing, X., & Sun, Z.
Venue
ACS Applied Materials & Interfaces
Published
2013-01-30
Volume
5
Issue
3
Pages
1078-1083
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2113641067
Cited by
520
References
2
FWCI
19.01
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+. https://app.cochat.ai/papers/10.1021/am302862k
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Zheng, M., Tan, H., Xie, Z., Zhang, L., Jing, X., & Sun, Z. (2013). Fast Response and High Sensitivity Europium Metal Organic Framework Fluorescent Probe with Chelating Terpyridine Sites for Fe3+. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am302862k

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