The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Mechanical and Viscoelastic Properties of Cellulose Nanocrystals Reinforced Poly(ethylene glycol) Nanocomposite Hydrogels
Abstract
The preparation and mechanical properties of elastomeric nanocomposite hydrogels consisting of cellulose nanocrystals (CNCs) and poly(ethylene glycol) (PEG) are reported. The aqueous nanocomposite CNC/PEG precursor solutions covalently cross-linked through a one-stage photocross-linking process. The mechanical properties of nanocomposite hydrogels, including Young's modulus (E), fracture stress (σ), and fracture strain (ε), were measured as a function of CNC volume fraction (φCNC, 0.2-1.8%, v/v) within polymeric matrix. It was found that the homogeneously dispersed nanocomposite hydrogels can be prepared with φCNC being less than 1.5%, whereas the heterogeneous nanocomposite hydrogels were obtained with φCNC being higher than 1.5%. The nanocomposite hydrogels exhibited higher strengths and flexibilities when compared with neat PEG hydrogels, where the modulus, fracture stress, and fracture strain enhanced by a factor of 3.48, 5, and 3.28, respectively, over the matrix material alone at 1.2% v/v CNC loading. Oscillatory shear data indicated the CNC-PEG nanocomposite hydrogels were more viscous than the neat PEG hydrogels and were efficient at energy dissipation due to the reversible interactions between CNC and PEG polymer chains. It was proposed that the strong gel viscoelastic behavior and the mechanical reinforcement were related to "filler network", where the temporary interactions between CNC and PEG interfered with the covalent cross-links of PEG.
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Cites
Double‐Network Hydrogels with Extremely High Mechanical Strength
Gong, J. P., Katsuyama, Y., Kurokawa, T., & Osada, Y. (2003) · Advanced Materials · doi:10.1002/adma.200304907 · Cited by 4,542
The Physics of Rubber Elasticity
G.Treloar, L. R. (2005) · doi:10.1093/oso/9780198570271.001.0001 · Cited by 2,253
The Polyrotaxane Gel: A Topological Gel by Figure-of-Eight Cross-links
Okumura, Y., & Ito, K. (2001) · Advanced Materials · doi:10.1002/1521-4095(200104)13:7<485::aid-adma485>3.0.co;2-t · Cited by 1,848
Theory of Filler Reinforcement
Guth, E. (1945) · Journal of Applied Physics · doi:10.1063/1.1707495 · Cited by 1,232
Supramolecular polymeric hydrogels
Appel, E. A., del Barrio, J., Loh, X. J., & Scherman, O. A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35264h · Cited by 1,159
Polymer nanocomposites reinforced by cellulose whiskers
Favier, V., Chanzy, H., & Cavaille, J. Y. (1995) · Macromolecules · doi:10.1021/ma00122a053 · Cited by 1,149
Hydrogels for Protein Delivery
Vermonden, T., Censi, R., & Hennink, W. E. (2012) · Chemical Reviews · doi:10.1021/cr200157d · Cited by 1,091
Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose
DONG, X. M., REVOL, J.-F., & GRAY, D. G. (1998) · Cellulose · doi:10.1023/a:1009260511939 · Cited by 1,032
Soft Nanotechnology with Soft Nanoparticles
Nayak, S., & Lyon, L. A. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501321 · Cited by 855
Cellulose nanowhiskers: promising materials for advanced applications
Eichhorn, S. J. (2011) · Soft Matter · doi:10.1039/c0sm00142b · Cited by 782
Large Strain Hysteresis and Mullins Effect of Tough Double-Network Hydrogels
Webber, R. E., Creton, C., Brown, H. R., & Gong, J. P. (2007) · Macromolecules · doi:10.1021/ma062924y · Cited by 702
Biopolymer-Based Hydrogels for Cartilage Tissue Engineering
Balakrishnan, B., & Banerjee, R. (2011) · Chemical Reviews · doi:10.1021/cr100123h · Cited by 547
Haraguchi, K., Li, H.-J., Matsuda, K., Takehisa, T., & Elliott, E. (2005) · Macromolecules · doi:10.1021/ma047431c · Cited by 499
Pei, A., Malho, J.-M., Ruokolainen, J., Zhou, Q., & Berglund, L. A. (2011) · Macromolecules · doi:10.1021/ma200318k · Cited by 421
Mechanical Properties and Structure of Polymer−Clay Nanocomposite Gels with High Clay Content
Haraguchi, K., & Li, H. (2006) · Macromolecules · doi:10.1021/ma052468y · Cited by 411
Goffin, A.-L., Raquez, J.-M., Duquesne, E., Siqueira, G., Habibi, Y., Dufresne, A., & Dubois, P. (2011) · Biomacromolecules · doi:10.1021/bm200581h · Cited by 395
High-Strength, Healable, Supramolecular Polymer Nanocomposites
Fox, J., Wie, J. J., Greenland, B. W., Burattini, S., Hayes, W., Colquhoun, H. M., Mackay, M. E., & Rowan, S. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300050x · Cited by 339
Large Strain and Fracture Properties of Poly(dimethylacrylamide)/Silica Hybrid Hydrogels
Lin, W.-C., Fan, W., Marcellan, A., Hourdet, D., & Creton, C. (2010) · Macromolecules · doi:10.1021/ma901937r · Cited by 314
Tingaut, P., Zimmermann, T., & Sèbe, G. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm32956e · Cited by 266
Cellulose Whisker/Epoxy Resin Nanocomposites
Tang, L., & Weder, C. (2010) · ACS Applied Materials & Interfaces · doi:10.1021/am900830h · Cited by 245
Lee, K., Tammelin, T., Schulfter, K., Kiiskinen, H. T., Samela, J., & Bismarck, A. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am300852a · Cited by 241
Abitbol, T., Johnstone, T., Quinn, T. M., & Gray, D. G. (2011) · Soft Matter · doi:10.1039/c0sm01172j · Cited by 227
Structure-mechanical property relationship of tough hydrogels
Shibayama, M. (2012) · Soft Matter · doi:10.1039/c2sm25325a · Cited by 193
Multipurpose smart hydrogel systems
Samchenko, Y., Ulberg, Z., & Korotych, O. (2011) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2011.06.005 · Cited by 184
Liu, H., Song, J., Shang, S., Song, Z., & Wang, D. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am3000209 · Cited by 183
Sehaqui, H., Zhou, Q., & Berglund, L. A. (2011) · Soft Matter · doi:10.1039/c1sm05325f · Cited by 165
Gel-nanocomposites: materials with promising applications
Das, D., Kar, T., & Das, P. K. (2012) · Soft Matter · doi:10.1039/c1sm06639k · Cited by 162
Yang, J. H., Han, C., Duan, J., Ma, M., Zhang, X., Xu, F., Sun, R., & Xie, X. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm35498e · Cited by 160
Self-citationPeresin, M. S., Habibi, Y., Vesterinen, A.-H., Rojas, O. J., Pawlak, J. J., & Seppälä, J. V. (2010) · Biomacromolecules · doi:10.1021/bm1006689 · Cited by 160
Mujtaba, A., Keller, M., Ilisch, S., Radusch, H. J., Thurn‐Albrecht, T., Saalwächter, K., & Beiner, M. (2012) · Macromolecules · doi:10.1021/ma300925p · Cited by 155
Cellulose-Nanofiber-Reinforced Poly(lactic acid) Composites Prepared by a Water-Based Approach
Wang, T., & Drzal, L. T. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am301438g · Cited by 149
Rusli, R., Shanmuganathan, K., Rowan, S. J., Weder, C., & Eichhorn, S. J. (2011) · Biomacromolecules · doi:10.1021/bm200141x · Cited by 141
Material Functionalization of Cellulose and Related Polysaccharides via Diverse Microcompositions
Nishio, Y. (2006) · Advances in polymer science · doi:10.1007/12_095 · Cited by 136
Polymer nanocomposites: structure, interaction, and functionality
Keledi, G., Hári, J., & Pukánszky, B. (2012) · Nanoscale · doi:10.1039/c2nr11442a · Cited by 121
Mechanical Properties of End-Linked PEG/PDMS Hydrogels
Cui, J., Lackey, M. A., Tew, G. N., & Crosby, A. J. (2012) · Macromolecules · doi:10.1021/ma300593g · Cited by 94
Aouada, F. A., de Moura, M. R., Orts, W. J., & Mattoso, L. H. C. (2011) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf202347h · Cited by 90
D’Errico, G., Lellis, M. D., Mangiapia, G., Tedeschi, A., Ortona, O., Fusco, S., Borzacchiello, A., & Ambrosio, L. (2007) · Biomacromolecules · doi:10.1021/bm7008137 · Cited by 72
Effect of polymer–particle interaction on the fracture toughness of silica filled hydrogels
Lin, W., Marcellan, A., Hourdet, D., & Creton, C. (2011) · Soft Matter · doi:10.1039/c1sm05420a · Cited by 59
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Hydrogel Bioink Reinforcement for Additive Manufacturing: A Focused Review of Emerging Strategies
Chimene, D., Kaunas, R., & Gaharwar, A. K. (2020) · Advanced Materials · doi:10.1002/adma.201902026 · Cited by 600
Metadata
- Authors
- Yang, J., Han, C.-R., Duan, J.-F., Xu, F., & Sun, R.-C.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-11
- Volume
- 5
- Issue
- 8
- Pages
- 3199-3207
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2014183919
- Cited by
- 261
- References
- 38
- FWCI
- 6.71
- Type
- journal article
- Language
- en
- Open access
- closed
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