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The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

Oxygen Vacancy Enhanced Photocatalytic Activity of Pervoskite SrTiO3

Tan, Huaqiao, Zhao, Zhao, Zhu, Wan-bin, Coker, Eric N., Li, Binsong, Zheng, Min, Yu, Weixing, Fan, Hongyou, Sun, Zaicheng·2014·ACS Applied Materials & Interfaces

Abstract

A facile and general method has been developed to fabricate oxygen vacancies on perovskite SrTiO3 (STO) nanocrystals through a controllable solid-state reaction of NaBH4 and SrTiO3 nanocrystals. STO samples with tunable color, oxygen vacancy concentration on nanocrystal surface have been synthesized. TEM results reveal that these STO samples have a crystalline core/amorphous shell structure (SrTiO3@SrTiO3-x). XPS and EPR results disclose that the oxygen vacancy concentration increases with the increase of reaction time and temperature. The concentration of oxygen vacancies calculated from TGA data, could reach 5.07% (atom) in this study. UV-vis spectra and photocatalytic results indicate that oxygen vacancies on STO surface play an important role in influencing the light absorption and photocatalytic performance. However, an excess amount of oxygen vacancies leads to a decrease of photocatalytic performance. The optimal photocatalytic activity for H2 production under UV-vis irradiation is up to 2.2 mmol h(-1) g(-1), which is about 2.3 times than the original SrTiO3, corresponding to 3.28% (atom) of oxygen vacancy concentration.

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Crossref · 10.1021/am5051907

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Metadata

Authors
Tan, H., Zhao, Z., Zhu, W.-B., Coker, E. N., Li, B., Zheng, M., Yu, W., Fan, H., & Sun, Z.
Venue
ACS Applied Materials & Interfaces
Published
2014-10-27
Volume
6
Issue
21
Pages
19184-19190
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2171345914
Cited by
806
References
3
FWCI
9.61
Type
journal article
Language
en
Open access
closed

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