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Cited by 293

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent

Open access
Luo, Wei, Bommier, Clement, Jian, Zelang, Li, Xin, Carter, Rich, Vail, Sean, Lu, Yuhao, Lee, Jong-Jan, Ji, Xiulei·2015·ACS Applied Materials & Interfaces

Abstract

Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In this study, we discover that doping graphene oxide into sucrose, the precursor for hard carbon, can effectively reduce the specific surface area of hard carbon to as low as 5.4 m(2)/g. We further reveal that such doping can effectively prevent foaming during caramelization of sucrose and extend the pyrolysis burnoff of sucrose caramel over a wider temperature range. The obtained low-surface-area hard carbon greatly improves the first-cycle Coulombic efficiency from 74% to 83% and delivers a very stable cyclic life with 95% of capacity retention after 200 cycles.

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Metadata

Authors
Luo, W., Bommier, C., Jian, Z., Li, X., Carter, R., Vail, S., Lu, Y., Lee, J.-J., & Ji, X.
Venue
ACS Applied Materials & Interfaces
Published
2015-01-20
Volume
7
Issue
4
Pages
2626-2631
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2013667701
Cited by
293
References
2
FWCI
17.32
Type
journal article
Language
en
Open access
green

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