The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Self-Assembled Block Copolymer Thin Films as Water Filtration Membranes
Abstract
Nanoporous membranes containing monodisperse pores of 24 nm diameter are fabricated using poly(styrene-b-lactide) block copolymers to template the pore structure. A 4 mum thin film of the block copolymer is cast onto a microporous membrane that provides mechanical reinforcement; by casting the copolymer film from the appropriate solvents and controlling the solvent evaporation rate, greater than 100 cm(2) of a thin film with polylactide cylinders oriented perpendicular to the thin dimension is produced. Exposing the composite membrane to a dilute aqueous base selectively etches the polylactide block, producing the porous structure. The ability of these pores to reject dissolved poly(ethylene oxide) molecules of varying molecular weight matches existing theories for transport through small pores.
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Citations
Cites
Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers
Zalusky, A. S., Olayo-Valles, R., Wolf, J. H., & Hillmyer, M. A. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0278584 · Cited by 553
Self-citation
Cited by
50th Anniversary Perspective: Block Polymers—Pure Potential
Bates, C. M., & Bates, F. S. (2017) · Macromolecules · doi:10.1021/acs.macromol.6b02355 · Cited by 788
Nanoporous Membranes Derived from Block Copolymers: From Drug Delivery to Water Filtration
Jackson, E. A., & Hillmyer, M. A. (2010) · ACS Nano · doi:10.1021/nn1014006 · Cited by 623
Self-citationControlled/Living Radical Polymerization in Dispersed Systems: An Update
Zetterlund, P. B., Thickett, S. C., Perrier, S., Bourgeat-Lami, E., & Lansalot, M. (2015) · Chemical Reviews · doi:10.1021/cr500625k · Cited by 485
Poly(lactide)-block-poly(ε-caprolactone-co-ε-decalactone)-block-poly(lactide) copolymer elastomers
Schneiderman, D. K., Hill, E. M., Martello, M. T., & Hillmyer, M. A. (2015) · Polymer Chemistry · doi:10.1039/c5py00202h · Cited by 101
Self-citationNeal, T. J., Neal, E. D., Cumby, J., & Garden, J. A. (2024) · Polymer Chemistry · doi:10.1039/d4py00169a · Cited by 12
Metadata
- Authors
- Phillip, W. A., O’Neill, B., Rodwogin, M., Hillmyer, M. A., & Cussler, E. L.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-02-26
- Volume
- 2
- Issue
- 3
- Pages
- 847-853
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2074386577
- Cited by
- 416
- References
- 1
- FWCI
- 13.75
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
