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Chiral Studies across the Spectrum of Polymer Science
Abstract
This Account describes how stereochemical ideas focused on chirality have been directed widely across polymer science allowing experiments that could not be conducted on small molecules and leading to new insights and new kinds of materials. In one approach, a helical polymer was studied, and it was discovered how the chiral information necessary to choose helical sense is greatly amplified. In another approach, the racemization kinetics of atropisomers were used to characterize the restrictions to motion associated with a polyelectrolyte that forms clusters around hydrophobic groups in water and in an entirely different system, the glassy state formed by polymers.
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Citations
Cited by
Chirality-Responsive Helical Polymers
Yashima, E., & Maeda, K. (2008) · Macromolecules · doi:10.1021/ma071453s · Cited by 441
A Simple γ-Backbone Modification Preorganizes Peptide Nucleic Acid into a Helical Structure
Dragulescu-Andrasi, A., Rapireddy, S., Frezza, B. M., Gayathri, C., Gil, R. R., & Ly, D. H. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0625576 · Cited by 286
Serine Octamers: Cluster Formation, Reactions, and Implications for Biomolecule Homochirality
Nanita, S. C., & Cooks, R. G. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200501328 · Cited by 184
Metadata
- Authors
- Green, M. M., Cheon, K.-S., Yang, S.-Y., Park, J.-W., Swansburg, S., & Liu, W.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-06-05
- Volume
- 34
- Issue
- 8
- Pages
- 672-680
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2059134344
- Cited by
- 183
- References
- 0
- FWCI
- 4.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Green, M. M., Cheon, K.-S., Yang, S.-Y., Park, J.-W., Swansburg, S., & Liu, W. (2001). Chiral Studies across the Spectrum of Polymer Science. Accounts of Chemical Research. https://doi.org/10.1021/ar010009l
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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