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Solid Acids for Green Chemistry
Abstract
Solid acids and especially those based on micelle-templated silicas and other mesoporous high surface area support materials are beginning to play a significant role in the greening of fine and specialty chemicals manufacturing processes. A wide range of important organic reactions can be efficiently catalyzed by these materials, which can be designed to provide different types of acidity as well as high degrees of reaction selectivity. The solid acids generally have high turnover numbers and can be easily separated from the organic components. The combination of this chemistry with innovative reaction engineering offers exciting opportunities for innovative green chemical manufacturing in the future.
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Cited by
Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels
Zhou, C.-H., Xia, X., Lin, C.-X., Tong, D.-S., & Beltramini, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15124j · Cited by 1,420
Hydrolysis of Cellulose by Amorphous Carbon Bearing SO3H, COOH, and OH Groups
Suganuma, S., Nakajima, K., Kitano, M., Yamaguchi, D., Kato, H., Hayashi, S., & Hara, M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja803983h · Cited by 1,020
Amorphous Carbon with SO3H Groups as a Solid Brønsted Acid Catalyst
Nakajima, K., & Hara, M. (2012) · ACS Catalysis · doi:10.1021/cs300103k · Cited by 435
Chew, T. L., & Bhatia, S. (2008) · Bioresource Technology · doi:10.1016/j.biortech.2008.03.009 · Cited by 337
Kitano, M., Yamaguchi, D., Suganuma, S., Nakajima, K., Kato, H., Hayashi, S., & Hara, M. (2009) · Langmuir · doi:10.1021/la8040506 · Cited by 289
Metadata
- Authors
- Clark, J. H.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-05-25
- Volume
- 35
- Issue
- 9
- Pages
- 791-797
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2114224286
- Cited by
- 665
- References
- 0
- FWCI
- 11.70
- Type
- journal article
- Language
- en
- Open access
- closed
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