The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Organolanthanide-Catalyzed Hydroamination
Abstract
Organolanthanides are highly efficient catalysts for inter- and intramolecular hydroamination of various C-C unsaturations such as alkenes, alkynes, allenes, and dienes. Attractive features of organolanthanide catalysts include very high turnover frequencies and excellent stereoselectivities, rendering this methodology applicable to concise synthesis of naturally occurring alkaloids and other polycyclic azacycles. The general hydroamination mechanism involves turnover-limiting C-C multiple bond insertion into the Ln-N bond, followed by rapid protonolysis by other amine substrates. Sterically less encumbered ligand designs have been developed to improve reaction rates, and metallocene and nonmetallocene chiral lanthanide complexes have been synthesized for enantioselective hydroamination.
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Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Gagne, M. R., Stern, C. L., & Marks, T. J. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00027a036 · Cited by 523
Self-citationJeske, G., Schock, L. E., Swepston, P. N., Schumann, H., & Marks, T. J. (1985) · Journal of the American Chemical Society · doi:10.1021/ja00312a051 · Cited by 345
Self-citationGribkov, D. V., Hultzsch, K. C., & Hampel, F. (2003) · Chemistry - A European Journal · doi:10.1002/chem.200304975 · Cited by 214
Ackermann, L., Bergman, R. G., & Loy, R. N. (2003) · Journal of the American Chemical Society · doi:10.1021/ja0361547 · Cited by 212
Douglass, M. R., Stern, C. L., & Marks, T. J. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010811i · Cited by 204
Self-citationDouglass, M. R., & Marks, T. J. (2000) · Journal of the American Chemical Society · doi:10.1021/ja993633q · Cited by 201
Self-citationStraub, T. S., Haskel, A., Gueta-Neyroud, T., Kapon, M., Botoshansky, M., & Eisen, M. S. (2001) · Organometallics · doi:10.1021/om010434i · Cited by 182
Organolanthanide-Catalyzed Intramolecular Hydroamination/Cyclization of Aminoallenes
Arredondo, V. M., McDonald, F. E., & Marks, T. J. (1998) · Journal of the American Chemical Society · doi:10.1021/ja9743248 · Cited by 169
Self-citationArredondo, V. M., McDonald, F. E., & Marks, T. J. (1999) · Organometallics · doi:10.1021/om981037j · Cited by 137
Self-citation
Cited by
Transition Metal‐Catalyzed Asymmetric Hydroamination of Alkenes (AHA)
Hultzsch, K. C. (2005) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200404261 · Cited by 486
Zhang, Z., Liu, C., Kinder, R. E., Han, X., Qian, H., & Widenhoefer, R. A. (2006) · Journal of the American Chemical Society · doi:10.1021/ja062045r · Cited by 459
Metadata
- Authors
- Hong, S., & Marks, T. J.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-06-29
- Volume
- 37
- Issue
- 9
- Pages
- 673-686
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2164076542
- Cited by
- 1,050
- References
- 11
- FWCI
- 39.61
- Type
- journal article
- Language
- en
- Open access
- closed
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