The DOI matches its Crossref record.
Predicting the Stereochemistry of Diphenylphosphino Benzoic Acid (DPPBA)-Based Palladium-Catalyzed Asymmetric Allylic Alkylation Reactions: A Working Model
Abstract
Palladium-catalyzed asymmetric allylic alkylation has proven to be a powerful method for the preparation of a wide variety of chiral compounds and the rapid assembly of complex molecular architecture from simple starting materials. While many types of catalyst systems have been successfully employed with certain systems, diphenylphosphino benzoic acid (DPPBA) based ligands have found use over a broad range of substrate classes. This Account highlights the mechanistic aspects considered when designing reactions with DPPBA-based ligands and presents a working model for the a priori prediction of their stereochemical outcome.
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Citations
Cited by
Trost, B. M., Zhang, T., & Sieber, J. D. (2010) · Chemical Science · doi:10.1039/c0sc00234h · Cited by 386
Self-citationAsymmetrische Gegenanionen‐vermittelte Katalyse: Konzept, Definition und Anwendungen
Mahlau, M., & List, B. (2013) · Angewandte Chemie · doi:10.1002/ange.201205343 · Cited by 313
Pierron, J., Malan, C., Creus, M., Gradinaru, J., Hafner, I., Ivanova, A., Sardo, A., & Ward, T. R. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200703159 · Cited by 117
Metadata
- Authors
- Trost, B. M., Machacek, M. R., & Aponick, A.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-07-26
- Volume
- 39
- Issue
- 10
- Pages
- 747-760
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2103380929
- Cited by
- 535
- References
- 0
- FWCI
- 9.37
- Type
- journal article
- Language
- en
- Open access
- closed
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