The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Polar Attributes of Supercritical Carbon Dioxide
Abstract
Supercritical carbon dioxide (scCO(2)) is increasingly promoted as an environmentally benign alternative to conventional organic solvents. The supercritical state bridges the gap between liquid and gaseous states by offering gaslike diffusion rates and liquidlike solvent densities, thereby enabling potential opportunities as a reaction and separation medium in chemical industry. Understanding the solvent behavior of liquid and scCO(2) is of critical importance to enable the design of CO(2)-philic molecular systems and to expand the use of these solvent systems to a wider range of chemical processes. Historically CO(2) was treated as a nonpolar solvent, primarily because of its low dielectric constant and zero molecular dipole moment. CO(2) has also been described as a quadrupolar solvent because of its significant quadrupole moment. Recent studies suggest that, as far as the microscopic solvent behavior of CO(2) is concerned, CO(2) has the potential to act as both a weak Lewis acid and Lewis base. Also, strong theoretical and experimental evidence indicates that CO(2) can participate in conventional or nonconventional hydrogen-bonding interactions. All of these site-specific solute-solvent interactions are important to understand the fundamental nature of CO(2) as a solvent. In this Account, we discuss these polar attributes of CO(2) and their relation to solvation.
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Citations
Cites
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Cited by
Bae, T., Lee, J. S., Qiu, W., Koros, W. J., Jones, C. W., & Nair, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201006141 · Cited by 678
Recent advances of inorganic fillers in mixed matrix membrane for gas separation
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Greening analytical chromatography
Welch, C. J., Wu, N., Biba, M., Hartman, R., Brkovic, T., Gong, X., Helmy, R., Schafer, W., Cuff, J., & Pirzada, Z. (2010) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2010.03.008 · Cited by 369
Davies, O. R., Lewis, A. L., Whitaker, M. J., Tai, H., Shakesheff, K. M., & Howdle, S. M. (2008) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2006.12.001 · Cited by 299
Metadata
- Authors
- Raveendran, P., Ikushima, Y., & Wallen, S. L.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-03
- Volume
- 38
- Issue
- 6
- Pages
- 478-485
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2138472891
- Cited by
- 316
- References
- 16
- FWCI
- 9.64
- Type
- journal article
- Language
- en
- Open access
- closed
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