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High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions
Abstract
High-valent iron(IV)-oxo species have been implicated as the key reactive intermediates in the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our understanding of the enzymatic reactions has improved greatly via investigation of spectroscopic and chemical properties of heme and non-heme iron(IV)-oxo complexes. In this Account, reactivities of synthetic iron(IV)-oxo porphyrin pi-cation radicals and mononuclear non-heme iron(IV)-oxo complexes in oxygenation reactions have been discussed as chemical models of cytochrome P450 and non-heme iron enzymes. These results demonstrate how mechanistic developments in biomimetic research can help our understanding of dioxygen activation and oxygen atom transfer reactions in nature.
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Cites
Structure and chemistry of cytochrome p450
Denisov, I. G., Makris, T. M., Sligar, S. G., & Schlichting, I. (2005) · Chemical Reviews · doi:10.1021/cr0307143 · Cited by 2,106
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Density functional theory for transition metals and transition metal chemistry
Cramer, C. J., & Truhlar, D. G. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b907148b · Cited by 1,648
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
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Andreini, C., Bertini, I., Cavallaro, G., Holliday, G. L., & Thornton, J. M. (2008) · JBIC Journal of Biological Inorganic Chemistry · doi:10.1007/s00775-008-0404-5 · Cited by 1,150
Xiao, D. J., Bloch, E. D., Mason, J. A., Queen, W. L., Hudson, M. R., Planas, N., Borycz, J., Dzubak, A. L., Verma, P., Lee, K., et al. (2014) · Nature Chemistry · doi:10.1038/nchem.1956 · Cited by 455
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Molecular Water Oxidation Mechanisms Followed by Transition Metals: State of the Art
Sala, X., Maji, S., Bofill, R., García-Antón, J., Escriche, L., & Llobet, A. (2014) · Accounts of Chemical Research · doi:10.1021/ar400169p · Cited by 313
Usharani, D., Lacy, D. C., Borovik, A. S., & Shaik, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408073m · Cited by 278
Metadata
- Authors
- Nam, W.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-01
- Volume
- 40
- Issue
- 7
- Pages
- 522-531
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2147899939
- Cited by
- 1,170
- References
- 1
- FWCI
- 42.52
- Type
- journal article
- Language
- en
- Open access
- closed
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