The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Role of Proton-Coupled Electron Transfer in O–O Bond Activation
Abstract
The selective reduction of oxygen to water requires four electrons and four protons. The design of catalysts that promote oxygen reduction therefore requires the management of both electron and proton inventories. Pacman and Hangman porphyrins provide a cleft for oxygen binding, a redox shuttle for oxygen reduction, and functionality for tuning the acid-base properties of bound oxygen and its intermediates. With proper control of the proton-coupled electron transfer events, O-O bond breaking of oxygen, and more generally oxygenated substrates, may be achieved with high efficiencies. The rule set developed for oxygen reduction may be applied to a variety of other small molecule activation reactions of consequence to energy conversion.
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Cites
Reece, S. Y., Hodgkiss, J. M., Stubbe, J., & Nocera, D. G. (2006) · Philosophical Transactions of the Royal Society B: Biological Sciences · doi:10.1098/rstb.2006.1874 · Cited by 294
Self-citation
Cited by
Theory of Coupled Electron and Proton Transfer Reactions
Hammes-Schiffer, S., & Stuchebrukhov, A. A. (2010) · Chemical Reviews · doi:10.1021/cr1001436 · Cited by 848
Chemistry of Personalized Solar Energy
Nocera, D. G. (2009) · Inorganic Chemistry · doi:10.1021/ic901328v · Cited by 395
Self-citationTheoretical Modeling of Electrochemical Proton-Coupled Electron Transfer
Warburton, R. E., Soudackov, A. V., & Hammes-Schiffer, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00929 · Cited by 322
Metadata
- Authors
- Rosenthal, J., & Nocera, D. G.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-27
- Volume
- 40
- Issue
- 7
- Pages
- 543-553
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2106604710
- Cited by
- 392
- References
- 1
- FWCI
- 11.73
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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