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Long-Distance Charge Transport in DNA: The Hopping Mechanism

Giese, Bernd·2000·Accounts of Chemical Research

Abstract

Long-distance charge transport from a guanine radical cation (G(+*)) to a G-rich sequence is of biological importance. This reaction was studied by selective charge injection into a G, monitoring the charge transport to a GGG sequence by competing H(2)O-trapping. The efficiency of the charge transport diminished dramatically with increasing number of A:T base pairs between G(+*) and GGG. But in DNA strands where G's are located between the G(+*) and GGG sequence, long-distance charge transport occurred by a multistep hopping mechanism.

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Metadata

Authors
Giese, B.
Venue
Accounts of Chemical Research
Published
2000-06-20
Volume
33
Issue
9
Pages
631-636
ISSN
  • 0001-4842 (ISSN-L)
  • 1520-4898
OpenAlex
W2093041725
Cited by
656
References
1
FWCI
18.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Long-Distance Charge Transport in DNA: The Hopping Mechanism. https://app.cochat.ai/papers/10.1021/ar990040b
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Giese, B. (2000). Long-Distance Charge Transport in DNA: The Hopping Mechanism. Accounts of Chemical Research. https://doi.org/10.1021/ar990040b

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