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Phosphoramidites: Marvellous Ligands in Catalytic Asymmetric Conjugate Addition
Open accessAbstract
The development of an efficient catalytic system for enantioselective carbon-carbon bond formation by 1,4-addition of organometallic reagents (organolithium, Grignard, and organozinc reagents) to enones is a major challenge in organic synthesis. This Account presents the breakthrough realized in this field using chiral phosphoramidite ligands for copper-catalyzed dialkylzinc additions. Applications in catalytic routes to cycloalkanones as well as tandem and annulation procedures with excellent enantioselectivities are discussed.
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Cited by
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Teichert, J. F., & Feringa, B. L. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200904948 · Cited by 710
Self-citationHighly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands
Reetz, M. T., & Mehler, G. (2000) · Angewandte Chemie · doi:10.1002/1521-3773(20001103)39:21<3889::aid-anie3889>3.0.co;2-t · Cited by 377
Catalyzed Asymmetric Arylation Reactions
Bolm, C., Hildebrand, J. P., Muñiz, K., & Hermanns, N. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010917)40:18<3284::aid-anie3284>3.0.co;2-u · Cited by 309
The emergence of sulfoxides as efficient ligands in transition metal catalysis
Sipos, G., Drinkel, E. E., & Dorta, R. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00524d · Cited by 283
Alexakis, A., Benhaim, C., Rosset, S., & Humam, M. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025598k · Cited by 277
Metadata
- Authors
- Feringa, B. L.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-05-31
- Volume
- 33
- Issue
- 6
- Pages
- 346-353
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2062487750
- Cited by
- 703
- References
- 0
- FWCI
- 25.85
- Type
- journal article
- Language
- en
- Open access
- green
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