The DOI matches its Crossref record.
The Kinetics and Mechanism of Formation of Metal Complexes
Abstract
Kinetic data for the formation of metal complexes obtained by various methods show that the complex formation of ML from metal ion, M, and ligand, L, can be described in terms of a rapid pre-equilibrium, involving formation of an outer sphere complex M(H 2 O)L, which then loses water in the rate-determining step of inner sphere complex (ML) formation. The formation rate is affected by electron configuration and oxidation state of M, the charge of the entering ligand, as well as ligands, including OHO -, already present. The metal-water exchange process is probably important in determining the rate of polymerization and formation of intermediates in redox processes.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Rickard, D., & Morse, J. W. (2005) · Marine Chemistry · doi:10.1016/j.marchem.2005.08.004 · Cited by 632
Mechanistic Studies of Metal Aqua Ions: A Semi‐Historical Perspective
Lincoln, S. F. (2005) · Helvetica Chimica Acta · doi:10.1002/hlca.200590036 · Cited by 110
A Comparison of Some Aspects of the Aqueous Coordination Chemistry of Aluminum(III) and Iron(III)
Crumbliss, A. L., & Garrison, J. M. (1988) · Comments on Inorganic Chemistry · doi:10.1080/02603598808048670 · Cited by 50
Metadata
- Authors
- EIGEN, M., & WILKINS, R. G.
- Venue
- Advances in Chemistry
- Publisher
- AMERICAN CHEMICAL SOCIETY
- Published
- 1965-01-01
- Pages
- 55-80
- ISSN
- 0065-2393 (ISSN-L)
- OpenAlex
- W2496076768
- Cited by
- 331
- References
- 0
- FWCI
- 6.37
- Type
- book chapter
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: The Kinetics and Mechanism of Formation of Metal Complexes. https://app.cochat.ai/papers/10.1021/ba-1965-0049.ch003
- The paper
- EIGEN, M., & WILKINS, R. G. (1965). The Kinetics and Mechanism of Formation of Metal Complexes. Advances in Chemistry. https://doi.org/10.1021/ba-1965-0049.ch003
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
