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Superabsorbent Polymers: Science and Technology
Abstract
Models developed to describe free radical crosslinking polymerizations may be divided into three classes: statistical models, kinetic descriptions, and kinetic gelation simulations. This paper provides a comparison of the three types of models by describing the approach, assumptions, strengths, and limitations of each when applied to lightly crosslinked systems. The greatest strength of the statistical approach arises from the wealth of post-gel structural information that can be obtained, however these models have difficulty accounting for history-dependent effects. Kinetic descriptions may properly describe history-dependent reaction non-idealities, but are unable to account for localized effects that are prevalent in highly crosslinked systems. The kinetic gelation simulations may describe topological constraints and localized effects but are of limited use for lightly crosslinked polymers due to their inability to accurately account for molecular motions.
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Cited by
Hydrogel-based devices for biomedical applications
Deligkaris, K., Tadele, T. S., Olthuis, W., & van den Berg, A. (2010) · Sensors and Actuators B: Chemical · doi:10.1016/j.snb.2010.03.083 · Cited by 451
Kabiri, K., Omidian, H., Hashemi, S. A., & Zohuriaan-Mehr, M. J. (2003) · European Polymer Journal · doi:10.1016/s0014-3057(02)00391-9 · Cited by 437
Acrylic acid/acrylamide based hydrogels and its properties - A review
Sennakesavan, G., Mostakhdemin, M., Dkhar, L. K., Seyfoddin, A., & Fatihhi, S. J. (2020) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2020.109308 · Cited by 409
Advances in non-hygienic applications of superabsorbent hydrogel materials
Zohuriaan-Mehr, M. J., Omidian, H., Doroudiani, S., & Kabiri, K. (2010) · Journal of Materials Science · doi:10.1007/s10853-010-4780-1 · Cited by 403
Sun, M.-L., Liu, S.-B., Qiao, L.-P., Chen, X.-L., Pang, X., Shi, M., Zhang, X.-Y., Qin, Q.-L., Zhou, B.-C., Zhang, Y.-Z., et al. (2014) · Applied Microbiology and Biotechnology · doi:10.1007/s00253-014-5839-8 · Cited by 39
Metadata
- Venue
- ACS Symposium Series
- Publisher
- American Chemical Society
- Published
- 1994-10-19
- ISSN
- 0097-6156 (ISSN-L)
- 1947-5918
- OpenAlex
- W2255639513
- Cited by
- 252
- References
- 0
- FWCI
- 8.05
- Type
- conference paper
- Language
- en
- Open access
- closed
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