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Controlled Radical Polymerization
Abstract
The fundamentals of controlled/"living" polymerization are discussed and the effects of slow initiation, transfer, termination and slow exchange on rates, molecular weights, polydispersities and end-functionalities are described. Some special features of and requirements for controlled radical polymerization are presented. Historical evolution of concepts leading to controlled radical polymerization is reviewed. Developments of several basic concepts in this field are summarized. Potential prospects for controlled radical reactions are evaluated.
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Citations
Cited by
Macromolecular architectures by living and controlled/living polymerizations
Hadjichristidis, N., Iatrou, H., Pitsikalis, M., & Mays, J. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.07.002 · Cited by 642
Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems
Qiu, J., Charleux, B., & Matyjaszewski, K. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00033-8 · Cited by 595
Self-citationBenoit, D., Harth, E., Fox, P., Waymouth, R. M., & Hawker, C. J. (2000) · Macromolecules · doi:10.1021/ma991187l · Cited by 216
Martín‐Gomis, L., Fernández‐García, M., de la Fuente, J. L., Madruga, E. L., & Cerrada, M. L. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300001 · Cited by 12
Metadata
- Venue
- ACS Symposium Series
- Publisher
- American Chemical Society
- Published
- 1998-01-08
- ISSN
- 0097-6156 (ISSN-L)
- 1947-5918
- OpenAlex
- W4230210408
- Cited by
- 412
- References
- 0
- FWCI
- 192.27
- Type
- conference paper
- Language
- en
- Open access
- closed
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- Controlled Radical Polymerization. (1998). ACS Symposium Series. https://doi.org/10.1021/bk-1998-0685
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
