The DOI matches its Crossref record; 21 of the 21 references it cites were found in a registry or an index.
Polymorphism of Cellulose I Family: Reinvestigation of Cellulose IVI
Abstract
Polymorphs of cellulose I, III(I), and IV(I) have been investigated by X-ray diffraction, FT-IR, and solid-state (13)C NMR spectroscopy. Highly crystalline cellulose III(I) samples were prepared by treating cellulose samples in supercritical ammonia at 140 degrees C for 1 h, and conventional cellulose III(I) samples were prepared by liquid ammonia treatment. The cellulose IV(I) sample of highest crystallinity was that prepared from Cladophora cellulose III(I) in supercritical ammonia, followed by the sample treated in glycerol at 260 degrees C for 0.5 h, whereas the lowest crystallinity was observed in ramie cellulose prepared by conventional liquid ammonia treatment followed by glycerol annealing. In general, the perfection of cellulose IV(I) depends on the crystallinity of the original material: either of the starting cellulose I or of the cellulose III(I) after ammonia treatment. The product thus obtained was analogous to cellulose I(beta), which is what it should be called rather than cellulose IV(I). If the existence of the polymorph cellulose IV(I) is not accepted, the observations on which it has been based may be explained by the fact that the structure termed cellulose IV(I) is cellulose I(beta) which contains lateral disorder.
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Cites
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Self-citationInfrared spectra of the crystalline modifications of cellulose
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Cited by
Abidi, N., Cabrales, L., & Haigler, C. H. (2014) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2013.01.074 · Cited by 658
Cellulose and the role of hydrogen bonds: not in charge of everything
Wohlert, M., Benselfelt, T., Wågberg, L., Furó, I., Berglund, L. A., & Wohlert, J. (2022) · Cellulose · doi:10.1007/s10570-021-04325-4 · Cited by 580
Structure and properties of the cellulose microfibril
Nishiyama, Y. (2009) · Journal of Wood Science · doi:10.1007/s10086-009-1029-1 · Cited by 567
Zuluaga, R., Putaux, J. L., Cruz, J., Vélez, J., Mondragon, I., & Gañán, P. (2009) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2008.09.024 · Cited by 448
Computer simulation studies of microcrystalline cellulose Iβ
Matthews, J. F., Skopec, C. E., Mason, P. E., Zuccato, P., Torget, R. W., Sugiyama, J., Himmel, M. E., & Brady, J. W. (2006) · Carbohydrate Research · doi:10.1016/j.carres.2005.09.028 · Cited by 398
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Metadata
- Authors
- Wada, M., Heux, L., & Sugiyama, J.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-05-14
- Volume
- 5
- Issue
- 4
- Pages
- 1385-1391
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W2065314779
- Cited by
- 310
- References
- 21
- FWCI
- 2.71
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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