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Cited by 279

The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.

“Green” Nanocomposites from Cellulose Acetate Bioplastic and Clay: Effect of Eco-Friendly Triethyl Citrate Plasticizer

Park, Hwan-Man, Misra, Manjusri, Drzal, Lawrence T., Mohanty, Amar K.·2004·Biomacromolecules

Abstract

"Green" nanocomposites have been successfully fabricated from cellulose acetate (CA) powder, eco-friendly triethyl citrate (TEC) plasticizer and organically modified clay. The effect of the amount of plasticizer varying from 15 to 40 wt % on the performance of the nanocomposites has been evaluated. The morphologies of these nanocomposites were evaluated through X-ray diffraction (XRD), atomic force microscopy (AFM), and transmission electron microscopy (TEM) studies. The mechanical properties of nanocomposites are correlated with the XRD and TEM observations. Cellulosic plastic-based nanocomposites with 20 wt % TEC plasticizer and 5 wt % organoclay showed better intercalation and an exfoliated structure than the counterpart having 30/40 wt % plasticizers. The tensile strength, modulus and thermal stability of cellulosic plastic reinforced with organoclay showed a decreasing trend with an increase of plasticizer content from 20 to 40 wt %. The nano-reinforcement at the lower volume fractions (phi < or = 0.02) reduced the water vapor permeability of cellulosic plastic by 2 times and the relative permeability better fits with larger platelet aspect ratios (alpha = 150).

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Crossref · 10.1021/bm049690f

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Metadata

Authors
Park, H.-M., Misra, M., Drzal, L. T., & Mohanty, A. K.
Venue
Biomacromolecules
Published
2004-09-10
Volume
5
Issue
6
Pages
2281-2288
ISSN
  • 1525-7797 (ISSN-L)
  • 1526-4602
OpenAlex
W1997397115
Cited by
279
References
18
FWCI
8.36
Type
journal article
Language
en
Open access
closed

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