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Cited by 424

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Surface Modification of Bacterial Cellulose Nanofibers for Property Enhancement of Optically Transparent Composites: Dependence on Acetyl-Group DS

Ifuku, Shinsuke, Nogi, Masaya, Abe, Kentaro, Handa, Keishin, Nakatsubo, Fumiaki, Yano, Hiroyuki·2007·Biomacromolecules

Abstract

Bacterial cellulose (BC) nanofibers were acetylated to enhance the properties of optically transparent composites of acrylic resin reinforced with the nanofibers. A series of BC nanofibers acetylated from degree-of-substitution (DS) 0 to 1.76 were obtained. X-ray diffraction profiles indicated that acetylation proceeded from the surface to the core of BC nanofibers, and scanning electron microscopy images showed that the volume of nanofibers increases by the bulky acetyl group. Since acetylation decreased the refractive index of cellulose, regular transmittance of composites comprised of 63% BC nanofiber was improved, and deterioration at 580 nm because of fiber reinforcement was suppressed to only 3.4%. Acetylation of nanofibers changed their surface properties and reduced the moisture content of the composite to about one-third that of untreated composite, although excessive acetylation increased hygroscopicity. Furthermore, acetylation was found to reduce the coefficient of thermal expansion of a BC sheet from 3 x 10(-6) to below 1 x 10(-6) 1/K.

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Metadata

Authors
Ifuku, S., Nogi, M., Abe, K., Handa, K., Nakatsubo, F., & Yano, H.
Venue
Biomacromolecules
Published
2007-04-26
Volume
8
Issue
6
Pages
1973-1978
ISSN
  • 1525-7797 (ISSN-L)
  • 1526-4602
OpenAlex
W2072946238
Cited by
424
References
1
FWCI
5.78
Type
journal article
Language
en
Open access
closed

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