The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Highly Filled Bionanocomposites from Functionalized Polysaccharide Nanocrystals
Abstract
Cellulose and starch nanocrystals obtained from the acid hydrolysis of ramie fibers and waxy maize starch granules, respectively, were subjected to isocyanate-mediated reaction to graft polycaprolactone (PCL) chains with various molecular weights on their surface. Grafted nanoparticles were characterized by X-ray diffraction analysis and contact angle measurements. We observed that the nanoparticles kept their initial morphological integrity and native crystallinity. Nanocomposite films were processed from both unmodified and PCL-grafted nanoparticles and PCL as matrix using a casting/evaporation technique. We showed that mechanical properties of resulting films were notably different. Compared to unmodified nanoparticles, the grafting of PCL chains on the surface results in lower modulus values but significantly higher strain at break. This unusual behavior clearly reflects the originality of the reinforcing phenomenon of polysaccharide nanocrystals resulting from the formation of a percolating network thanks to chain entanglements and cocrystallization.
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Cites
Rodlike cellulose microcrystals: Structure, properties and applications
de Souza Lima, M. M., & Borsali, R. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200300268 · Cited by 894
Sugiyama, J., Vuong, R., & Chanzy, H. (1991) · Macromolecules · doi:10.1021/ma00014a033 · Cited by 791
Structure and thermal properties of poly(lactic acid)/cellulose whiskers nanocomposite materials
Petersson, L., Kvien, I., & Oksman, K. (2007) · Composites Science and Technology · doi:10.1016/j.compscitech.2006.12.012 · Cited by 576
Morphological investigation of nanocomposites from sorbitol plasticized starch and tunicin whiskers
Mathew, A. P., & Dufresne, A. (2002) · Biomacromolecules · doi:10.1021/bm0101769 · Cited by 384
Self-citationNanocomposites of Chitin Whiskers from Riftia Tubes and Poly(caprolactone)
Morin, A., & Dufresne, A. (2002) · Macromolecules · doi:10.1021/ma011493a · Cited by 287
Self-citationA high strength nanocomposite based on microcrystalline cellulose and polyurethane
Wu, Q., Henriksson, M., Liu, X., & Berglund, L. A. (2007) · Biomacromolecules · doi:10.1021/bm701061t · Cited by 265
Orientation of cellulose nanowhiskers in polyvinyl alcohol
Kvien, I., & Oksman, K. (2007) · Applied Physics A · doi:10.1007/s00339-007-3882-3 · Cited by 176
Starch Nanocrystal Fillers in an Acrylic Polymer Matrix
Angellier, H., Putaux, J., Molina‐Boisseau, S., Dupeyre, D., & Dufresne, A. (2005) · Macromolecular Symposia · doi:10.1002/masy.200550310 · Cited by 106
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Cited by
Cellulose nanomaterials review: structure, properties and nanocomposites
Moon, R. J., Martini, A., Nairn, J., Simonsen, J., & Youngblood, J. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00108b · Cited by 6,756
Cellulose nanocrystals: chemistry, self-assembly, and applications
Habibi, Y., Lucia, L. A., & Rojas, O. J. (2010) · Chemical Reviews · doi:10.1021/cr900339w · Cited by 5,980
Self-citationProduction of nanocrystalline cellulose from lignocellulosic biomass: Technology and applications
Brinchi, L., Cotana, F., Fortunati, E., & Kenny, J. M. (2013) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2013.01.033 · Cited by 1,121
Cellulose nanocrystals and related nanocomposites: Review of some properties and challenges
Mariano, M., El Kissi, N., & Dufresne, A. (2014) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23490 · Cited by 933
Self-citationCellulosic nanocomposites: a review
(2008) · BioResources · doi:10.15376/biores.3.3.929-980 · Cited by 901
Metadata
- Authors
- Habibi, Y., & Dufresne, A.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-05-30
- Volume
- 9
- Issue
- 7
- Pages
- 1974-1980
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W2003599729
- Cited by
- 373
- References
- 8
- FWCI
- 7.97
- Type
- journal article
- Language
- en
- Open access
- closed
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