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Iron-Based Metal–Organic Frameworks MIL-88B and NH2-MIL-88B: High Quality Microwave Synthesis and Solvent-Induced Lattice “Breathing”
Abstract
Iron-based MIL-88B and NH 2 -MIL-88B microcrystals with high dispersibility and uniform size were successfully synthesized by using a rapid microwave-assisted solvothermal method. By carefully controlling the reaction conditions, the microwave method provided superior quality MIL-88B crystals in high yields and excellent phase purity. Framework flexibility was observed for both MIL-88B-Fe and NH 2 -MIL-88B-Fe frameworks in various solvents, which however significantly differs between the two materials. MIL-88B-Fe shrinks reversibly by about 25% only when it is dispersed in the strongly hydrogen bonding solvents water or methanol. In contrast, NH 2 -MIL-88B-Fe shrinks up to 33% upon replacement of dimethylformamide (DMF) by any other solvent studied (benzene, chloroform, acetone, acetonitrile, methanol, water). The change in unit cell parameters (shortening of the a axis) can be seen macroscopically, although the overall integrity of the materials is maintained. We suggest that hydrogen bonding between the oxygen atoms of the MIL-88B-Fe framework and solvent molecules plays an important role in the framework shrinkage, while in the NH 2 -MIL-88B-Fe framework additional hydrogen bonds may form and thus a different breathing behavior is observed.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications
McKinlay, A. C., Morris, R. E., Horcajada, P., Férey, G., Gref, R., Couvreur, P., & Serre, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000048 · Cited by 1,256
Cited by
Liu, X., Zhou, Y., Zhang, J., Tang, L., Luo, L., & Zeng, G. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02563 · Cited by 312
Biocompatibility and biodegradability of metal organic frameworks for biomedical applications
Singh, N., Qutub, S., & Khashab, N. M. (2021) · Journal of Materials Chemistry B · doi:10.1039/d1tb01044a · Cited by 303
Metadata
- Authors
- Ma, M., Bétard, A., Weber, I., Al-Hokbany, N. S., Fischer, R. A., & Metzler-Nolte, N.
- Venue
- Crystal Growth & Design
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-24
- Volume
- 13
- Issue
- 6
- Pages
- 2286-2291
- ISSN
- 1528-7483 (ISSN-L)
- 1528-7505
- OpenAlex
- W2326211557
- Cited by
- 298
- References
- 2
- FWCI
- 3.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ma, M., Bétard, A., Weber, I., Al-Hokbany, N. S., Fischer, R. A., & Metzler-Nolte, N. (2013). Iron-Based Metal–Organic Frameworks MIL-88B and NH2-MIL-88B: High Quality Microwave Synthesis and Solvent-Induced Lattice “Breathing”. Crystal Growth & Design. https://doi.org/10.1021/cg301738p
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