The DOI matches its Crossref record.
Powder Synthesis and Characterization of Amorphous Carbon Nitride
Abstract
Carbon nitride powder has been prepared by solid-state reaction between cyanuric chloride or its fluoro analogue and lithium nitride. The determined, by elemental analysis, atomic N/C ratio (1.33) in the synthesized material is entirely consistent with the C 3 N 4 stoichiometry. Combined material characterization data, obtained by Fourier transform infrared, Raman, UV−visible, ( 13 C) magic-angle spinning NMR, X-ray photoelectron spectroscopy, thermal gravimetric analysis/differential thermal analysis, and pyrolysis−electron ionization mass spectrometry methods, provide substantial evidence for graphite-like sp 2 -bonded structure composed of building blocks of s-triazine rings bridged by the 3-fold coordinated nitrogen atoms in the bulk carbon nitride. As indicated by X-ray and scanning electron microscopy analytical data, the material is amorphous and changes from turbostratic to more ordered layered graphitic morphology under high pressures. The availability of stoichiometric carbon nitride a -C 3 N 4 in gram quantities, made possible by a developed low-cost synthetic method, facilitates the extensive studies of bulk processing and electromechanical properties, and high-pressure/high-temperature transformations of this material into superhard crystalline polymorphic phases.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Wang, Y., Wang, X., & Antonietti, M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201101182 · Cited by 3,364
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Dong, G., Zhang, Y., Pan, Q., & Qiu, J. (2014) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2014.04.002 · Cited by 1,085
Metadata
- Authors
- Khabashesku, V. N., Zimmerman, J. L., & Margrave, J. L.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-10-07
- Volume
- 12
- Issue
- 11
- Pages
- 3264-3270
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W4249534044
- Cited by
- 623
- References
- 0
- FWCI
- 4.53
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Powder Synthesis and Characterization of Amorphous Carbon Nitride. https://app.cochat.ai/papers/10.1021/cm000328r
- The paper
- Khabashesku, V. N., Zimmerman, J. L., & Margrave, J. L. (2000). Powder Synthesis and Characterization of Amorphous Carbon Nitride. Chemistry of Materials. https://doi.org/10.1021/cm000328r
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
