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Anchoring of Phosphonate and Phosphinate Coupling Molecules on Titania Particles
Abstract
Titanium oxide particles were treated using six organophosphorus compounds chosen as model coupling molecules: phenylphosphonic and diphenylphosphinic acids, their ethyl esters, and their trimethylsilyl esters. The ability of all of these coupling molecules to modify the surface of the TiO 2 particles was demonstrated by elemental analysis, thermogravimetric analysis, and nitrogen adsorption. The bonding modes on the surface were investigated by means of diffuse reflectance IR Fourier transform (DRIFT) and 31 P solid-state MAS NMR spectroscopy. Upon irradiation in water, a marked trend to the photooxidative degradation of the anchored organophosphorus groups was evidenced, especially in the case of phosphinate groups.
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Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
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Bioinspired catecholic chemistry for surface modification
Ye, Q., Zhou, F., & Liu, W. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15026j · Cited by 1,177
Surface Modification and Functionalization of Metal and Metal Oxide Nanoparticles by Organic Ligands
Neouze, M.-A., & Schubert, U. (2008) · Monatshefte für Chemie - Chemical Monthly · doi:10.1007/s00706-007-0775-2 · Cited by 538
Comparelli, R., Fanizza, E., Curri, M. L., Cozzoli, P. D., Mascolo, G., & Agostiano, A. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2005.02.013 · Cited by 300
Mutin, P. H., & Vioux, A. (2009) · Chemistry of Materials · doi:10.1021/cm802348c · Cited by 296
Self-citationWaßmann, M., Winkel, A., Haak, K., Dempwolf, W., Stiesch, M., & Menzel, H. (2016) · Journal of Biomaterials Science Polymer Edition · doi:10.1080/09205063.2016.1214001 · Cited by 15
Metadata
- Authors
- Guerrero, G., Mutin, P. H., & Vioux, A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-10-13
- Volume
- 13
- Issue
- 11
- Pages
- 4367-4373
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2093348224
- Cited by
- 540
- References
- 1
- FWCI
- 12.51
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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