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Metastable MnS Crystallites through Solvothermal Synthesis

Lu, Jun, Qi, Pengfei, Peng, Yiya, Meng, Zhaoyu, Yang, Zhiping, Yu, Weichao, Qian, Yitai·2001·Chemistry of Materials

Abstract

Metastable (β and γ) and stable (α) MnS crystallites were synthesized by solvothermal reaction in various solvents at 190−200 °C. In tetrahydrofuran and benzene, the metastable MnS crystallites can be obtained. In water, ammonia liquor, ethylenediamine, α-MnS, which is converted from the metastable phase, would be obtained. The low solubility of MnS is the crucial reason to stabilize the metastable phase with good yield. The metastable MnS crystallites were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and transmission electron microscopy. The metastable γ-MnS crystallites with rodlike morphology were found, and a unique “methane-like” four-branched rod cluster was characterized. The blue shift of the absorption edge indicates the quantum size effect of metastable MnS nanocrystallites.

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Metadata

Authors
Lu, J., Qi, P., Peng, Y., Meng, Z., Yang, Z., Yu, W., & Qian, Y.
Venue
Chemistry of Materials
Published
2001-06-01
Volume
13
Issue
6
Pages
2169-2172
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2951798295
Cited by
162
References
1
FWCI
3.77
Type
journal article
Language
en
Open access
closed

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