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Cited by 192

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Synthesis and Characterization of Soluble Iron Oxide−Dendrimer Composites

Strable, Erica, Bulte, Jeff W. M., Moskowitz, Bruce, Vivekanandan, Kannan, Allen, Mark, Douglas, Trevor·2001·Chemistry of Materials

Abstract

Carboxylated poly(amidoamine) PAMAM dendrimers (generation 4.5) have been utilized for the synthesis and stabilization of ferrimagnetic iron oxide nanoparticles. Oxidation of Fe(II) at slightly elevated pH and temperature results in the formation of highly soluble nanocomposites of iron oxides and dendrimer, which are stable under a wide range of temperatures and pH's. Size exclusion chromatography indicates aggregates in the 20−30-nm size regime, consistent with the oligomeric nature of the composite material. Transmission electron microscopy reveals small assemblies of mineral cores with electron diffraction and high-resolution TEM data, indicative of the mineral maghemite. SQUID magnetometry demonstrated that this crystalline composition exhibited superparamagnetism at room temperature. NMR relaxation studies of solvent (water) protons revealed unusually high T1 and T2 relaxivities, which make these materials excellent candidates as contrast agents for MR imaging.

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Metadata

Authors
Strable, E., Bulte, J. W. M., Moskowitz, B., Vivekanandan, K., Allen, M., & Douglas, T.
Venue
Chemistry of Materials
Published
2001-05-23
Volume
13
Issue
6
Pages
2201-2209
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2087475991
Cited by
192
References
2
FWCI
13.15
Type
journal article
Language
en
Open access
closed

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