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Photocatalysis and Photoinduced Hydrophilicity of Various Metal Oxide Thin Films

Miyauchi, Masahiro, Nakajima, Akira, Watanabe, Toshiya, Hashimoto, Kazuhito·2002·Chemistry of Materials

Abstract

Thin films of various metal oxides were prepared on glass substrates by a wet process to determine their photocatalytic ability to decompose adsorbed dye and to evaluate their photoinduced hydrophilicity under UV illumination. The metal oxides used in this study are classified into four categories based on their behavior over the two photochemical reaction: (1) active in both photocatalytic oxidation and photoinduced hydrophilicity (TiO 2, SnO 2, ZnO); (2) only active in photocatalytic oxidation (SrTiO 3 ); (3) only active in photoinduced hydrophilicity (WO 3, V 2 O 5 ); (4) and inactive over both processes (CeO 2, CuO, MoO 3, Fe 2 O 3, Cr 2 O 3, In 2 O 3 ). X-ray photoelectron spectroscopy revealed that oxygen defect sites were produced by Ar + bombardment on the surface of metal oxides, showing photoinduced hydrophilicity. These results indicate that photoinduced hydrophilicity is not induced by the photocatalytic oxidation of organic compounds adsorbed on the surface, but is based on structural changes of the metal oxide surfaces.

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Metadata

Authors
Miyauchi, M., Nakajima, A., Watanabe, T., & Hashimoto, K.
Venue
Chemistry of Materials
Published
2002-05-15
Volume
14
Issue
6
Pages
2812-2816
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2025914103
Cited by
649
References
42
FWCI
7.76
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Photocatalysis and Photoinduced Hydrophilicity of Various Metal Oxide Thin Films. https://app.cochat.ai/papers/10.1021/cm020076p
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Miyauchi, M., Nakajima, A., Watanabe, T., & Hashimoto, K. (2002). Photocatalysis and Photoinduced Hydrophilicity of Various Metal Oxide Thin Films. Chemistry of Materials. https://doi.org/10.1021/cm020076p

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.