The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
One-Step Low-Temperature Route for the Preparation of Electrochemically Active LiMnPO4 Powders
Abstract
Pure and well-crystallized LiMnPO 4 powders were obtained by a direct precipitation route in an aqueous medium at 373 K. A thermodynamic study of the system Li + /Mn(II)/phosphate/H 2 O identified a pH range in which LiMnPO 4 precipitation was the most probable. From these theoretical considerations, the olivine-type compound precipitation turned out to be straightforward, i.e., no further thermal treatment was needed. A systematic study of the influence of synthesis parameters enabled tailoring of the size of the as-obtained particles. The smallest precipitated particles (∼100 nm) led to a global improvement of the electrochemical behavior when used in lithium batteries, consisting in lowering the polarization and enhancement of the reversible capacities (∼70 mAh/g at C/20). A two-phase Li extraction/insertion mechanism was identified, using the potential intermittent titration technique (PITT) and in situ X-ray diffraction, between LiMnPO 4 and the delithiated phase MnPO 4, indexed in the space group Pmnb with unit cell parameters a = 5.93(2) Å, b = 9.69(6) Å, and c = 4.78(1) Å.
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Citations
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Cited by
Prospective materials and applications for Li secondary batteries
Jeong, G., Kim, Y.-U., Kim, H., Kim, Y.-J., & Sohn, H.-J. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00831a · Cited by 616
Recent advances in the research of polyanion-type cathode materials for Li-ion batteries
Gong, Z., & Yang, Y. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00713g · Cited by 549
LiMnPO4 – A next generation cathode material for lithium-ion batteries
Aravindan, V., Gnanaraj, J., Lee, Y.-S., & Madhavi, S. (2013) · Journal of Materials Chemistry A · doi:10.1039/c2ta01393b · Cited by 466
LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-Ion Battery Cathode
Choi, D., Wang, D., Bae, I.-T., Xiao, J., Nie, Z., Wang, W., Viswanathan, V. V., Lee, Y. J., Zhang, J.-G., Graff, G. L., et al. (2010) · Nano Letters · doi:10.1021/nl1007085 · Cited by 367
Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries
Whittingham, M. S., Song, Y., Lutta, S., Zavalij, P. Y., & Chernova, N. A. (2005) · Journal of Materials Chemistry · doi:10.1039/b501961c · Cited by 296
Metadata
- Authors
- Delacourt, C., Poizot, P., Morcrette, M., Tarascon, J.-M., & Masquelier, C.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-12-12
- Volume
- 16
- Issue
- 1
- Pages
- 93-99
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2949768999
- Cited by
- 406
- References
- 1
- FWCI
- 11.06
- Type
- journal article
- Language
- en
- Open access
- closed
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