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Contribution of X-ray Photoelectron Spectroscopy to the Study of the Electrochemical Reactivity of CoO toward Lithium
Abstract
The positive attributes of X-ray photoelectron spectroscopy to the field of battery research is illustrated through the study of reaction mechanisms involved during the electrochemical reduction/oxidation of a metal oxide (MO) electrode vs Li. Through the acquisition and interpretation of various (Co 2p, Li 1s, O 1s, and C 1s) XPS spectra during the charge and discharge of a CoO/Li battery, we could confirm the reversibility of the CoO → Co conversion reaction process involving the reversible formation/decomposition of CoO and Li 2 O together with the reversible growth of an organic layer. More importantly, such measurements suggested that the organic polymer could contain, among others, oligomer chains of poly(ethylene oxide) (CH 2 CH 2 O) n .
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Hüfner, S. (1995) · Springer Series in Solid-State Sciences · doi:10.1007/978-3-662-03150-6 · Cited by 854
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Han, X., Yu, C., Yang, J., Zhao, C., Huang, H., Liu, Z., Ajayan, P. M., & Qiu, J. (2016) · Advanced Materials Interfaces · doi:10.1002/admi.201500782 · Cited by 234
Yu, M., Waag, F., Chan, C. K., Weidenthaler, C., Barcikowski, S., & Tüysüz, H. (2020) · ChemSusChem · doi:10.1002/cssc.201903186 · Cited by 93
Flower-like porous cobalt(II) monoxide nanostructures as anode material for Li-ion batteries
Jena, A., Penki, T. R., Munichandraiah, N., & Shivashankar, S. A. (2016) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2015.11.003 · Cited by 73
Metadata
- Authors
- Dedryvère, R., Laruelle, S., Grugeon, S., Poizot, P., Gonbeau, D., & Tarascon, J.-M.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-02-26
- Volume
- 16
- Issue
- 6
- Pages
- 1056-1061
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2068361543
- Cited by
- 338
- References
- 1
- FWCI
- 11.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dedryvère, R., Laruelle, S., Grugeon, S., Poizot, P., Gonbeau, D., & Tarascon, J.-M. (2004). Contribution of X-ray Photoelectron Spectroscopy to the Study of the Electrochemical Reactivity of CoO toward Lithium. Chemistry of Materials. https://doi.org/10.1021/cm0311269
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