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Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy

Waddon, Alan. J., Coughlin, E. Bryan·2003·Chemistry of Materials

Abstract

The crystal structure and morphology of inorganic−organic hybrid POSS nanoparticles, consisting of an inorganic core of silicon and oxygen and outer organic attachments of alkyl groups, has been studied using X-ray diffraction and electron microscopy. These molecules self-assemble to form a hexagonally packed structure. Alkyl attachments are accommodated within the interstices of the hexagonal lattice. The results have implications for our understanding of the disorder in polymer−POSS nanocomposite materials such as those formed by copolymerization.

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Metadata

Authors
Waddon, A. J., & Coughlin, E. B.
Venue
Chemistry of Materials
Published
2003-11-01
Volume
15
Issue
24
Pages
4555-4561
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W1970393504
Cited by
241
References
0
FWCI
6.57
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy. https://app.cochat.ai/papers/10.1021/cm034308b
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Waddon, A. J., & Coughlin, E. B. (2003). Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy. Chemistry of Materials. https://doi.org/10.1021/cm034308b

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.