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Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy
Abstract
The crystal structure and morphology of inorganic−organic hybrid POSS nanoparticles, consisting of an inorganic core of silicon and oxygen and outer organic attachments of alkyl groups, has been studied using X-ray diffraction and electron microscopy. These molecules self-assemble to form a hexagonally packed structure. Alkyl attachments are accommodated within the interstices of the hexagonal lattice. The results have implications for our understanding of the disorder in polymer−POSS nanocomposite materials such as those formed by copolymerization.
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Cited by
Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes
Cordes, D. B., Lickiss, P. D., & Rataboul, F. (2010) · Chemical Reviews · doi:10.1021/cr900201r · Cited by 1,613
Polyhedral Oligomeric Silsesquioxanes (POSS)-Containing Nanohybrid Polymers
Pielichowski, K., Njuguna, J., Janowski, B., & Pielichowski, J. (2006) · Advances in Polymer Science · doi:10.1007/12_077 · Cited by 372
Biodegradable Thermoplastic Polyurethanes Incorporating Polyhedral Oligosilsesquioxane
Knight, P. T., Lee, K. M., Qin, H., & Mather, P. T. (2008) · Biomacromolecules · doi:10.1021/bm8004935 · Cited by 141
Improved shape memory performance of star-shaped POSS-polylactide based polyurethanes (POSS-PLAUs)
Gu, S. Y., & Gao, X. F. (2015) · RSC Advances · doi:10.1039/c5ra14742e · Cited by 29
Metadata
- Authors
- Waddon, A. J., & Coughlin, E. B.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-11-01
- Volume
- 15
- Issue
- 24
- Pages
- 4555-4561
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1970393504
- Cited by
- 241
- References
- 0
- FWCI
- 6.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy. https://app.cochat.ai/papers/10.1021/cm034308b
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- Waddon, A. J., & Coughlin, E. B. (2003). Crystal Structure of Polyhedral Oligomeric Silsequioxane (POSS) Nano-materials: A Study by X-ray Diffraction and Electron Microscopy. Chemistry of Materials. https://doi.org/10.1021/cm034308b
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