The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si
Abstract
Alkyl-capped and alkyl/alkoxy-capped silicon nanocrystals have been prepared by the oxidation of magnesium silicide with bromine. High-resolution transmission electron microscopy confirmed the crystalline nature of the nanoparticles and provided an average diameter of 4.5 (2.0) nm for the alkyl-capped and for the alkyl/alkoxy-capped nanoparticles. Energy-dispersive X-ray spectroscopy showed that the nanoparticles are composed of silicon, with no evidence of unreacted bromine. FTIR spectra were consistent with alkyl- and alkyl/alkoxy-capped surfaces. Fluorescence spectroscopy indicated strong ultraviolet-blue photoluminescence, which was attributed to both quantum confinement and surface termination. These nanoparticles displayed long-term stability and no degradation of the photoluminescence was observed for a period of 1 year.
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Cites
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Cited by
Algar, W. R., Prasuhn, D. E., Stewart, M. H., Jennings, T. L., Blanco-Canosa, J. B., Dawson, P. E., & Medintz, I. L. (2011) · Bioconjugate Chemistry · doi:10.1021/bc200065z · Cited by 502
Zhukhovitskiy, A. V., MacLeod, M. J., & Johnson, J. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00220 · Cited by 363
SYNTHESIS ROUTES FOR LARGE VOLUMES OF NANOPARTICLES
Masala, O., & Seshadri, R. (2004) · Annual Review of Materials Research · doi:10.1146/annurev.matsci.34.052803.090949 · Cited by 355
Dasog, M., De los Reyes, G. B., Titova, L. V., Hegmann, F. A., & Veinot, J. G. C. (2014) · ACS Nano · doi:10.1021/nn504109a · Cited by 334
Silicon quantum dots: surface matters
Dohnalová, K., Gregorkiewicz, T., & Kůsová, K. (2014) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/26/17/173201 · Cited by 253
Metadata
- Authors
- Pettigrew, K. A., Liu, Q., Power, P. P., & Kauzlarich, S. M.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-08-30
- Volume
- 15
- Issue
- 21
- Pages
- 4005-4011
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2018205856
- Cited by
- 166
- References
- 1
- FWCI
- 5.30
- Type
- journal article
- Language
- en
- Open access
- closed
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