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Cited by 166

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Solution Synthesis of Alkyl- and Alkyl/Alkoxy-Capped Silicon Nanoparticles via Oxidation of Mg2Si

Pettigrew, Katherine A., Liu, Qi, Power, Philip P., Kauzlarich, Susan M.·2003·Chemistry of Materials

Abstract

Alkyl-capped and alkyl/alkoxy-capped silicon nanocrystals have been prepared by the oxidation of magnesium silicide with bromine. High-resolution transmission electron microscopy confirmed the crystalline nature of the nanoparticles and provided an average diameter of 4.5 (2.0) nm for the alkyl-capped and for the alkyl/alkoxy-capped nanoparticles. Energy-dispersive X-ray spectroscopy showed that the nanoparticles are composed of silicon, with no evidence of unreacted bromine. FTIR spectra were consistent with alkyl- and alkyl/alkoxy-capped surfaces. Fluorescence spectroscopy indicated strong ultraviolet-blue photoluminescence, which was attributed to both quantum confinement and surface termination. These nanoparticles displayed long-term stability and no degradation of the photoluminescence was observed for a period of 1 year.

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Metadata

Authors
Pettigrew, K. A., Liu, Q., Power, P. P., & Kauzlarich, S. M.
Venue
Chemistry of Materials
Published
2003-08-30
Volume
15
Issue
21
Pages
4005-4011
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2018205856
Cited by
166
References
1
FWCI
5.30
Type
journal article
Language
en
Open access
closed

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