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Cited by 782

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Formation and Stability of Size-, Shape-, and Structure-Controlled CdTe Nanocrystals: Ligand Effects on Monomers and Nanocrystals

Yu, W. William, Wang, Y. Andrew, Peng, Xiaogang·2003·Chemistry of Materials

Abstract

The formation of nearly monodisperse CdTe nanocrystals dots (either zinc blende or wurtzite crystal structure), rods, and tetrapods in a noncoordinating solvent was studied. Several strong ligand effects were observed, and the ligand effects on the monomers were found to play a more important role than the ligand effects on the nanocrystals. Experimental results suggest that, instead of monomer concentrations, monomer activities is a more relevant term for understanding the formation of nanocrystals because strong ligands always exist in the reaction solutions. The bonding strength and the steric effects of ligands dramatically affect the reactivity of monomers and are considered as contributors to the activity coefficients of monomers. The overall optical properties of the as-prepared CdTe nanocrystals are better than those reported in the literature and comparable to the standard CdSe nanocrystal system. The configuration of the hydrocarbon chains of the ligands on the surface of each nanocrystal also plays a critical role in determining the stability of CdTe nanocrystals.

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Metadata

Authors
Yu, W. W., Wang, Y. A., & Peng, X.
Venue
Chemistry of Materials
Published
2003-10-03
Volume
15
Issue
22
Pages
4300-4308
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2035500973
Cited by
782
References
2
FWCI
16.11
Type
journal article
Language
en
Open access
closed

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