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Replication of Mesoporous Aluminosilicate Molecular Sieves (RMMs) with Zeolite Framework from Mesoporous Carbons (CMKs)
Abstract
A novel class of mesoporous aluminosilicate molecular sieves has been prepared by replication from carbon mesoporous molecular sieves (CMKs) using zeolite precursors and characterized by a variety of analytical and spectroscopic techniques, such as XRD, N 2 adsorption/desorption, SEM/TEM, IR, hyperpolarized (HP) 129 Xe, and 31 P MAS NMR. These replicated mesoporous materials (RMMs), namely RMM-1 and RMM-3 prepared from CMK-1 and CMK-3, were found to exhibit mesoporous structures respectively analogous to Al-MCM-48 and Al-SBA-15 but possess unique microporous characteristics due to the presence of zeolite secondary building units in the framework. Consequently, these RMMs are also found to have superior thermal, hydrothermal, and mechanical stabilities and with improved acidic properties compared to their respective parent counterparts. The RMM-3 so prepared represents the first synthesis of protonated aluminosilicate with an SBA-15 structure prepared by a nonacidic route.
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Citations
Cited by
Hierarchically porous materials: synthesis strategies and structure design
Yang, X.-Y., Chen, L.-H., Li, Y., Rooke, J. C., Sanchez, C., & Su, B.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00829a · Cited by 1,439
Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity
Choi, M., Cho, H. S., Srivastava, R., Venkatesan, C., Choi, D.-H., & Ryoo, R. (2006) · Nature Materials · doi:10.1038/nmat1705 · Cited by 1,152
Self-citationHierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Synthesis of non-siliceous mesoporous oxides
Gu, D., & Schüth, F. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60155b · Cited by 584
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Li, K., Valla, J., & Garcia‐Martinez, J. (2014) · ChemCatChem · doi:10.1002/cctc.201300345 · Cited by 470
Metadata
- Authors
- Sakthivel, A., Huang, S.-J., Chen, W.-H., Lan, Z.-H., Chen, K.-H., Kim, T.-W., Ryoo, R., Chiang, A. S. T., & Liu, S.-B.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-07-13
- Volume
- 16
- Issue
- 16
- Pages
- 3168-3175
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2025090394
- Cited by
- 178
- References
- 0
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Replication of Mesoporous Aluminosilicate Molecular Sieves (RMMs) with Zeolite Framework from Mesoporous Carbons (CMKs). https://app.cochat.ai/papers/10.1021/cm035293k
- The paper
- Sakthivel, A., Huang, S.-J., Chen, W.-H., Lan, Z.-H., Chen, K.-H., Kim, T.-W., Ryoo, R., Chiang, A. S. T., & Liu, S.-B. (2004). Replication of Mesoporous Aluminosilicate Molecular Sieves (RMMs) with Zeolite Framework from Mesoporous Carbons (CMKs). Chemistry of Materials. https://doi.org/10.1021/cm035293k
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