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Solventless Synthesis of Bi2S3 (Bismuthinite) Nanorods, Nanowires, and Nanofabric
Abstract
Orthorhombic Bi 2 S 3 (bismuthinite) nanorods and nanowires are synthesized by the solventless thermolysis of bismuth alkylthiolate precursors. Reactions carried out in air at ∼225 °C in the presence of a capping ligand species, octanoate, produce high aspect ratio (>100) nanowires. Lower aspect ratio nanowires (∼7) are produced by the same approach with the addition of elemental sulfur at lower reaction temperature (∼160 °C). Both the nanowires and nanorods are oriented with their long axes in the [002] crystallographic direction. Higher reaction temperatures (∼250 °C) produce crossed nanowire networks, or fabrics, with highly oriented growth as a result of heterogeneous nanowire nucleation and epitaxial elongation off the surface of existing wires.
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Cites
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols
LaMer, V. K., & Dinegar, R. H. (1950) · Journal of the American Chemical Society · doi:10.1021/ja01167a001 · Cited by 3,894
Cited by
Zhang, B., Ye, X., Hou, W., Zhao, Y., & Xie, Y. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp060769j · Cited by 351
Crystal Splitting in the Growth of Bi2S3
Tang, J., & Alivisatos, A. P. (2006) · Nano Letters · doi:10.1021/nl0615930 · Cited by 326
Metadata
- Authors
- Sigman, M. B., & Korgel, B. A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-03-04
- Volume
- 17
- Issue
- 7
- Pages
- 1655-1660
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2060967170
- Cited by
- 203
- References
- 1
- FWCI
- 10.28
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sigman, M. B., & Korgel, B. A. (2005). Solventless Synthesis of Bi2S3 (Bismuthinite) Nanorods, Nanowires, and Nanofabric. Chemistry of Materials. https://doi.org/10.1021/cm0478733
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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