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Phase Behavior of Ionic Liquid−LiX Mixtures: Pyrrolidinium Cations and TFSI- Anions
Abstract
Phase diagrams are reported for mixtures between bis(trifluoromethanesulfonyl)imide (TFSI - ) salts containing Li + and N -alkyl- N -methylpyrrolidinium (PYR 1R + ) cations. The latter salts readily form both room temperature ionic liquids and plastic crystalline phases. Mixed salt crystalline phases are found which are likely to influence the performance of such mixed salt systems when utilized as electrolytes for electrochemical devices as well as give insight into ionic liquid−solute interactions.
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Citations
Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
How Ionic Are Room-Temperature Ionic Liquids? An Indicator of the Physicochemical Properties
Tokuda, H., Tsuzuki, S., Susan, M. A. B. H., Hayamizu, K., & Watanabe, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp064159v · Cited by 1,206
Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
MacFarlane, D. R., Forsyth, M., Howlett, P. C., Pringle, J. M., Sun, J., Annat, G., Neil, W., & Izgorodina, E. I. (2007) · Accounts of Chemical Research · doi:10.1021/ar7000952 · Cited by 710
Castner, E. W., & Wishart, J. F. (2010) · The Journal of Chemical Physics · doi:10.1063/1.3373178 · Cited by 398
Metadata
- Authors
- Henderson, W. A., & Passerini, S.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-07-01
- Volume
- 16
- Issue
- 15
- Pages
- 2881-2885
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1991830045
- Cited by
- 297
- References
- 0
- FWCI
- 5.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Henderson, W. A., & Passerini, S. (2004). Phase Behavior of Ionic Liquid−LiX Mixtures: Pyrrolidinium Cations and TFSI- Anions. Chemistry of Materials. https://doi.org/10.1021/cm049942j
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