The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Novel Photochromic Molecules Based on 4,5-Dithienyl Thiazole with Fast Thermal Bleaching Rate
Abstract
Novel photochromic triangle terarylenes are synthesized, and their photochromic properties and thermal bleaching kinetics are investigated. Fairly high photochemical coloration reactivity is observed with photochemical quantum yield as high as 0.6 for 4,5-dithienyl thiazole derivative. Introduction of phenyl-ethynyl groups into the molecular structure allows systematic control of thermal cycloreversion time constant over 10 5 times, and the half-lifetime shorter than 2 s is achieved at 303 K. The kinetic analysis of thermal cycloreversion reaction clearly shows significant contribution of frequency factor A . A novel molecular designing concept for systematic control of thermal bleaching reaction rate is presented without taking bulky functional groups on reaction center.
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Cites
Ablation, Flux, and Atmospheric Implications of Meteors Inferred from Stratospheric Aerosol
Cziczo, D. J., Thomson, D. S., & Murphy, D. M. (2001) · Science · doi:10.1126/science.1057737 · Cited by 176
Cited by
Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators
Irie, M., Fukaminato, T., Matsuda, K., & Kobatake, S. (2014) · Chemical Reviews · doi:10.1021/cr500249p · Cited by 2,725
Molecular photoswitches in aqueous environments
Volarić, J., Szymanski, W., Simeth, N. A., & Feringa, B. L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00547a · Cited by 438
Metadata
- Authors
- Kawai, S., Nakashima, T., Atsumi, K., Sakai, T., Harigai, M., Imamoto, Y., Kamikubo, H., Kataoka, M., & Kawai, T.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-09
- Volume
- 19
- Issue
- 14
- Pages
- 3479-3483
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2073170681
- Cited by
- 160
- References
- 1
- FWCI
- 2.93
- Type
- journal article
- Language
- en
- Open access
- closed
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