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Preparation of Microporous Carbon Fibers through Carbonization of Al-Based Porous Coordination Polymer (Al-PCP) with Furfuryl Alcohol

Radhakrishnan, Logudurai, Reboul, Julien, Furukawa, Shuhei, Srinivasu, Pavuluri, Kitagawa, Susumu, Yamauchi, Yusuke·2011·Chemistry of Materials

Abstract

Here, we report preparation of microporous carbon fibers through carbonization of an Al-based porous coordination polymer (Al-PCP) with furfuryl alcohol (FA) at 1000 °C under an inert gas atmosphere. During the carbonization process, the Al species are aggregated to form γ-alumina nanoparticles. After the carbonization, the γ-alumina nanoparticles (from 2 to 10 nm) are distributed over the entire area. By chemical treatment with HF, the γ-alumina nanoparticles can be easily removed to obtain pure microporous carbon. Interestingly, the fibrous morphology of the original Al-PCP is successfully retained after the carbonization process. The effect of the loading amount of FA into the porous networks of Al-PCP on properties of the obtained microporous carbon is carefully examined. From the N 2 adsorption−desorption isotherms, an increase in the BET surface area upon increasing the loading amount of FA is observed. The maximum surface area and pore volume of the obtained microporous carbon reach 513 m 2 /g and 0.844 cc/g, respectively.

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Metadata

Authors
Radhakrishnan, L., Reboul, J., Furukawa, S., Srinivasu, P., Kitagawa, S., & Yamauchi, Y.
Venue
Chemistry of Materials
Published
2011-01-27
Volume
23
Issue
5
Pages
1225-1231
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2324760783
Cited by
240
References
3
FWCI
10.53
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Preparation of Microporous Carbon Fibers through Carbonization of Al-Based Porous Coordination Polymer (Al-PCP) with Furfuryl Alcohol. https://app.cochat.ai/papers/10.1021/cm102921y
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Radhakrishnan, L., Reboul, J., Furukawa, S., Srinivasu, P., Kitagawa, S., & Yamauchi, Y. (2011). Preparation of Microporous Carbon Fibers through Carbonization of Al-Based Porous Coordination Polymer (Al-PCP) with Furfuryl Alcohol. Chemistry of Materials. https://doi.org/10.1021/cm102921y

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