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Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries
Abstract
Mn 3 O 4 has been investigated as a high-capacity anode material for rechargeable lithium ion batteries. Spongelike nanosized Mn 3 O 4 was synthesized by a simple precipitation method and characterized by powder X-ray diffraction, Raman scattering and scanning electron microscopy. Its electrochemical performance, as an anode material, was evaluated by galvanostatic discharge–charge tests. The results indicate that this novel type of nanosized Mn 3 O 4 exhibits a high initial reversible capacity (869 mA h/g) and significantly enhanced first Coulomb efficiency with a stabilized reversible capacity of around 800 mA h/g after over 40 charge/discharge cycles.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Arora, P., Doyle, M., & White, R. E. (1999) · Journal of The Electrochemical Society · doi:10.1149/1.1392512 · Cited by 586
Cited by
Faraji, S., & Ani, F. N. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.03.144 · Cited by 417
Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material
Zheng, J., Xu, P., Gu, M., Xiao, J., Browning, N. D., Yan, P., Wang, C., & Zhang, J.-G. (2015) · Chemistry of Materials · doi:10.1021/cm5045978 · Cited by 405
Manganese Oxide/Carbon Yolk–Shell Nanorod Anodes for High Capacity Lithium Batteries
Cai, Z., Xu, L., Yan, M., Han, C., He, L., Hercule, K. M., Niu, C., Yuan, Z., Xu, W., Qu, L., et al. (2015) · Nano Letters · doi:10.1021/nl504427d · Cited by 366
Metadata
- Authors
- Gao, J., Lowe, M. A., & Abruña, H. D.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-13
- Volume
- 23
- Issue
- 13
- Pages
- 3223-3227
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2019811197
- Cited by
- 370
- References
- 2
- FWCI
- 22.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, J., Lowe, M. A., & Abruña, H. D. (2011). Spongelike Nanosized Mn3O4 as a High-Capacity Anode Material for Rechargeable Lithium Batteries. Chemistry of Materials. https://doi.org/10.1021/cm201039w
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