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Composition-Controlled Synthesis of Bimetallic PdPt Nanoparticles and Their Electro-oxidation of Methanol

Liu, Yi, Chi, Miaofang, Mazumder, Vismadeb, More, Karren L., Soled, Stuart, Henao, Juan D., Sun, Shouheng·2011·Chemistry of Materials

Abstract

PdPt alloy nanoparticles (NPs) are promising catalysts for various chemical reactions because of the presence of powerful catalytic components of Pt and Pd on the surface of one nanostructure. In this paper, we report a facile synthesis of polyhedral PdPt alloy NPs via coreduction of Pd(acac) 2 (acac = acetylacetonate) and Pt(acac) 2 with morpholine borane in oleylamine at 90 and 180 °C. In the synthesis, the molar ratio of the two metal precursors added in the reaction mixture was carried over to the final PdPt NP product, and compositions of the PdPt NPs were readily tuned from Pd 88 Pt 12 to Pd 34 Pt 66 . These PdPt NPs show the composition-dependent catalytic activity for methanol oxidation, with NPs in 40–60 atomic % Pt exhibiting the superior activity and durability.

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Cites

Research works printed but not linked: 20

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Metadata

Authors
Liu, Y., Chi, M., Mazumder, V., More, K. L., Soled, S., Henao, J. D., & Sun, S.
Venue
Chemistry of Materials
Published
2011-08-19
Volume
23
Issue
18
Pages
4199-4203
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W257740838
Cited by
241
References
6
FWCI
8.80
Type
journal article
Language
en
Open access
closed

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