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Covalent Triazine Frameworks Prepared from 1,3,5-Tricyanobenzene
Abstract
A novel covalent triazine framework (CTF-0) was prepared by trimerization of 1,3,5-tricyanobenzene in molten ZnCl 2 . The monomer/ZnCl 2 ratio, the reaction time, and temperature significantly influence the structure and porosity of such networks. XRD measurements revealed that crystalline frameworks can be formed with surface areas around 500 m 2 ·g –1 and high CO 2 uptakes. Increasing the reaction temperature yielded an amorphous material with an enlarged surface area of 2000 m 2 ·g –1 . This material showed good catalytic activity for CO 2 cycloaddition.
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Cited by
Covalent Organic Framework Photocatalysts: Structures and Applications
Wang, H., Wang, H., Wang, Z., Tang, L., Zeng, G., Xu, P., Chen, M., Xiong, T., Zhou, C., Li, X., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00278j · Cited by 1,301
Mitra, S., Sasmal, H. S., Kundu, T., Kandambeth, S., Illath, K., Díaz Díaz, D., & Banerjee, R. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b00925 · Cited by 587
Phenyl-triazine oligomers for light-driven hydrogen evolution
Schwinghammer, K., Hug, S., Mesch, M. B., Senker, J., & Lotsch, B. V. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02574e · Cited by 273
Metadata
- Authors
- Katekomol, P., Roeser, J., Bojdys, M., Weber, J., & Thomas, A.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-02
- Volume
- 25
- Issue
- 9
- Pages
- 1542-1548
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2012055701
- Cited by
- 436
- References
- 0
- FWCI
- 14.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Covalent Triazine Frameworks Prepared from 1,3,5-Tricyanobenzene. https://app.cochat.ai/papers/10.1021/cm303751n
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- Katekomol, P., Roeser, J., Bojdys, M., Weber, J., & Thomas, A. (2013). Covalent Triazine Frameworks Prepared from 1,3,5-Tricyanobenzene. Chemistry of Materials. https://doi.org/10.1021/cm303751n
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