The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Effect of Ferroelectricity on Solar-Light-Driven Photocatalytic Activity of BaTiO3—Influence on the Carrier Separation and Stern Layer Formation
Open accessAbstract
BaTiO 3 is used as a target catalyst to probe the influence of ferroelectricity on the decolorization of a typical dye molecule—Rhodamine B—under simulated solar light. We show that there is a 3-fold increase in the decolorization rate using BaTiO 3 with a high tetragonal content compared to predominantly cubic material. This is ascribed to the ferroelectricity of the tetragonal phase. The influence of ferroelectricity ensures a tightly bound layer of dye molecule and also acts to separate the photoexcited carriers due to the internal space charge layer. Both of these features act to enhance the catalytic performance. When nanostructured Ag is photochemically deposited on the surface of the BaTiO 3, we find a further increase in the reaction rate that gives complete decolorization of the dye in around 45 min.
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Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Progress, challenge and perspective of heterogeneous photocatalysts
Qu, Y., & Duan, X. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35355e · Cited by 1,466
Structures of the ferroelectric phases of barium titanate
Kwei, G. H., Lawson, A. C., Billinge, S. J. L., & Cheong, S. W. (1993) · The Journal of Physical Chemistry · doi:10.1021/j100112a043 · Cited by 777
Cited by
Nanostructured materials for photocatalysis
Xu, C., Ravi Anusuyadevi, P., Aymonier, C., Luque, R., & Marre, S. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00102f · Cited by 1,082
Liang, Z., Yan, C.-F., Rtimi, S., & Bandara, J. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.09.028 · Cited by 689
Yu, D., Liu, Z., Zhang, J., Li, S., Zhao, Z., Zhu, L., Liu, W., Lin, Y., Liu, H., & Zhang, Z. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.01.095 · Cited by 367
Coupling Piezocatalysis and Photocatalysis in Bi4NbO8X (X = Cl, Br) Polar Single Crystals
Hu, C., Huang, H., Chen, F., Zhang, Y., Yu, H., & Ma, T. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201908168 · Cited by 367
Insights into the Role of Ferroelectric Polarization in Piezocatalysis of Nanocrystalline BaTiO3
Wu, J., Xu, Q., Lin, E., Yuan, B., Qin, N., Thatikonda, S. K., & Bao, D. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b01991 · Cited by 357
Metadata
- Authors
- Cui, Y., Briscoe, J., & Dunn, S.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-17
- Volume
- 25
- Issue
- 21
- Pages
- 4215-4223
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2325413950
- Cited by
- 549
- References
- 3
- FWCI
- 8.54
- Type
- journal article
- Language
- en
- Open access
- green
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