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MAPbI3-xClx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties

Colella, Silvia, Mosconi, Edoardo, Fedeli, Paolo, Listorti, Andrea, Gazza, Francesco, Orlandi, Fabio, Ferro, Patrizia, Besagni, Tullo, Rizzo, Aurora, Calestani, Gianluca, Gigli, Giuseppe, De Angelis, Filippo, Mosca, Roberto·2013·Chemistry of Materials

Abstract

Hybrid halide perovskites represent one of the most promising solutions toward the fabrication of all solid nanostructured solar cells, with improved efficiency and long-term stability. This article aims at investigating the structural properties of iodide/chloride mixed-halide perovskites and correlating them with their photovoltaic performances. We found out that, independent of the components ratio in the precursor solution, Cl incorporation in an iodide-based structure, is possible only at relatively low concentration levels (below 3–4%). However, even if the material band gap remains substantially unchanged, the Cl doping dramatically improves the charge transport within the perovskite layer, explaining the outstanding performances of meso-superstructured solar cells based on this material.

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Metadata

Authors
Colella, S., Mosconi, E., Fedeli, P., Listorti, A., Gazza, F., Orlandi, F., Ferro, P., Besagni, T., Rizzo, A., Calestani, G., Gigli, G., De Angelis, F., & Mosca, R.
Venue
Chemistry of Materials
Published
2013-11-11
Volume
25
Issue
22
Pages
4613-4618
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2005868847
Cited by
796
References
1
FWCI
63.11
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: MAPbI3-xClx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties. https://app.cochat.ai/papers/10.1021/cm402919x
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Colella, S., Mosconi, E., Fedeli, P., Listorti, A., Gazza, F., Orlandi, F., Ferro, P., Besagni, T., Rizzo, A., Calestani, G., Gigli, G., De Angelis, F., & Mosca, R. (2013). MAPbI3-xClx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties. Chemistry of Materials. https://doi.org/10.1021/cm402919x

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