The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Core/Shell Structured La- and Rh-Codoped SrTiO3 as a Hydrogen Evolution Photocatalyst in Z-Scheme Overall Water Splitting under Visible Light Irradiation
Abstract
The effects of preparation methods, calcination times, and La doping concentrations on the crystallinity, visible light absorption, and photocatalytic water splitting performance of Rh- and La-codoped SrTiO 3 (SrTiO 3:La/Rh) were investigated. Applying a two-step solid state reaction in which SrTiO 3 acted as a perovskite-type host produced core/shell structured SrTiO 3:La/Rh, the surface of which was enriched with the dopants. La doping suppressed the formation of oxygen vacancies and inactive Rh 4+ species. Under visible light irradiation (λ > 420 nm), SrTiO 3:La/Rh exhibited 3.5 and 3.8 times higher rates of H 2 evolution in an aqueous methanol solution and during redox-free Z-scheme overall water splitting in combination with Ir/CoO x /Ta 3 N 5, respectively, compared to SrTiO 3:Rh. The solar-to-hydrogen efficiency of the Z-scheme system as measured under illumination with simulated sunlight (AM1.5G) was found to have improved by a factor of 3.
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Cites
Iwashina, K., & Kudo, A. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2050315 · Cited by 457
Cited by
Wang, Q., Hisatomi, T., Jia, Q., Tokudome, H., Zhong, M., Wang, C., Pan, Z., Takata, T., Nakabayashi, M., Shibata, N., et al. (2016) · Nature Materials · doi:10.1038/nmat4589 · Cited by 1,684
Self-citationZ‐Scheme Photocatalytic Systems for Solar Water Splitting
Ng, B., Putri, L. K., Kong, X. Y., Teh, Y. W., Pasbakhsh, P., & Chai, S. (2020) · Advanced Science · doi:10.1002/advs.201903171 · Cited by 533
Gunawan, D., Zhang, J., Li, Q., Toe, C. Y., Scott, J., Antonietti, M., Guo, J., & Amal, R. (2024) · Advanced Materials · doi:10.1002/adma.202404618 · Cited by 325
Zhang, Q., Huang, Y., Xu, L., Cao, J.-J., Ho, W., & Lee, S. C. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b11887 · Cited by 161
Hollow CaTiO3 cubes modified by La/Cr co-doping for efficient photocatalytic hydrogen production
Wang, R., Ni, S., Liu, G., & Xu, X. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.11.061 · Cited by 132
Metadata
- Authors
- Wang, Q., Hisatomi, T., Ma, S. S. K., Li, Y., & Domen, K.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-03
- Volume
- 26
- Issue
- 14
- Pages
- 4144-4150
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2059146064
- Cited by
- 301
- References
- 1
- FWCI
- 8.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Q., Hisatomi, T., Ma, S. S. K., Li, Y., & Domen, K. (2014). Core/Shell Structured La- and Rh-Codoped SrTiO3 as a Hydrogen Evolution Photocatalyst in Z-Scheme Overall Water Splitting under Visible Light Irradiation. Chemistry of Materials. https://doi.org/10.1021/cm5011983
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