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Synthesis and Electrochemical Property of Boron-Doped Mesoporous Carbon in Supercapacitor
Abstract
Mesoporous carbon with homogeneous boron dopant was prepared by co-impregnation and carbonization of sucrose and boric acid confined in mesopores of SBA-15 silica template. Low-level boron doping shows catalytic effect on oxygen chemisorption at edge planes and alters electronic structure of space charge layer of doped mesoporous carbon. These characteristics are responsible for substantial improvement of interfacial capacitance by 1.5−1.6 times higher in boron-doped carbon than that in boron-free carbon with alkaline electrolyte (6 M KOH) and/or acid electrolyte (1 M H 2 SO 4 ). This finding should be very useful for developing new doped carbon electrode materials for supercapacitors.
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Citations
Cited by
Wang, Q., Yan, J., & Fan, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03109e · Cited by 1,225
Nitrogen-containing microporous carbon nanospheres with improved capacitive properties
Su, F., Poh, C. K., Chen, J. S., Xu, G., Wang, D., Li, Q., Lin, J., & Lou, X. W. (2011) · Energy Environ. Sci. · doi:10.1039/c0ee00277a · Cited by 916
Self-citationTemplated nanocarbons for energy storage
Nishihara, H., & Kyotani, T. (2012) · Advanced Materials · doi:10.1002/adma.201201715 · Cited by 745
Carbonaceous Electrode Materials for Supercapacitors
Hao, L., Li, X., & Zhi, L. (2013) · Advanced Materials · doi:10.1002/adma.201301204 · Cited by 710
Carbon-Based Fibers for Advanced Electrochemical Energy Storage Devices
Chen, S., Qiu, L., & Cheng, H.-M. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00466 · Cited by 555
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Metadata
- Authors
- Wang, D.-W., Li, F., Chen, Z.-G., Lu, G. Q., & Cheng, H.-M.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-25
- Volume
- 20
- Issue
- 22
- Pages
- 7195-7200
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2017456432
- Cited by
- 554
- References
- 0
- FWCI
- 5.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, D.-W., Li, F., Chen, Z.-G., Lu, G. Q., & Cheng, H.-M. (2008). Synthesis and Electrochemical Property of Boron-Doped Mesoporous Carbon in Supercapacitor. Chemistry of Materials. https://doi.org/10.1021/cm801729y
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