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Synthesis and Characterization of Hexagonally Packed Mesoporous Tantalum Oxide Molecular Sieves
Abstract
The synthesis and characterization of Ta-TMS1, a new member of a growing family of hexagonally packed transition-metal oxide mesoporous molecular sieves (termed TMS1) is described. Ta-TMS1 exhibits a hexagonal array of pores which can be varied in size from 20 to 40 Å and surface areas of over 500 m 2 /g. The thermal and hydrothermal stabilities of Ta-TMS1 are 500 and 450 °C, respectively, making this system the most stable transition-metal oxide molecular sieve yet isolated. The high hydrocarbon adsorption capacities of this material make it a promising candidate as a catalyst support for hydrocarbon re-forming processes. The synthesis of this material was achieved by a novel approach involving the careful hydrolysis of long-chain primary amine complexes of Ta(OEt) 5 . This ligand-assisted templating mechanism represents a new approach to the synthesis of porous materials in that the inorganic precursor is covalently bonded to the template throughout synthesis. The high thermal stability, ease of synthesis and doping, and high surface areas of this material make it competitive with zeolitic molecular sieve materials and may lead to a wide variety of commercial applications.
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Citations
Cites
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., & Beck, J. S. (1992) · Nature · doi:10.1038/359710a0 · Cited by 16,275
(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Beck, J. S., Vartuli, J. C., Roth, W. J., Leonowicz, M. E., Kresge, C. T., Schmitt, K. D., Chu, C. T. W., Olson, D. H., Sheppard, E. W., McCullen, S. B., et al. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00053a020 · Cited by 10,967
Comprehensive Coordination Chemistry
Eaborn, C. (1988) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(88)83103-6 · Cited by 7,163
Generalized synthesis of periodic surfactant/inorganic composite materials
Huo, Q., Margolese, D. I., Ciesla, U., Feng, P., Gier, T. E., Sieger, P., Leon, R., Petroff, P. M., Schüth, F., & Stucky, G. D. (1994) · Nature · doi:10.1038/368317a0 · Cited by 2,087
Titanium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds
Tanev, P. T., Chibwe, M., & Pinnavaia, T. J. (1994) · Nature · doi:10.1038/368321a0 · Cited by 1,774
Cooperative Formation of Inorganic-Organic Interfaces in the Synthesis of Silicate Mesostructures
Monnier, A., Schüth, F., Huo, Q., Kumar, D., Margolese, D., Maxwell, R. S., Stucky, G. D., Krishnamurty, M., Petroff, P., Firouzi, A., et al. (1993) · Science · doi:10.1126/science.261.5126.1299 · Cited by 1,569
Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays
Huo, Q., Margolese, D. I., Ciesla, U., Demuth, D. G., Feng, P., Gier, T. E., Sieger, P., Firouzi, A., & Chmelka, B. F. (1994) · Chemistry of Materials · doi:10.1021/cm00044a016 · Cited by 1,483
Synthesis of Hexagonally Packed Mesoporous TiO2 by a Modified Sol–Gel Method
Antonelli, D. M., & Ying, J. Y. (1995) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199520141 · Cited by 1,109
Self-citationStudies on mesoporous materials
Chen, C.-Y., Li, H.-X., & Davis, M. E. (1993) · Microporous Materials · doi:10.1016/0927-6513(93)80058-3 · Cited by 943
Cooperative Organization of Inorganic-Surfactant and Biomimetic Assemblies
Firouzi, A., Kumar, D., Bull, L. M., Besier, T., Sieger, P., Huo, Q., Walker, S. A., Zasadzinski, J. A., Glinka, C., Nicol, J., et al. (1995) · Science · doi:10.1126/science.7855591 · Cited by 777
Maatta, E. (1989) · Organometallics · doi:10.1021/om00114a601 · Cited by 667
Vartuli, J. C., Schmitt, K. D., Kresge, C. T., Roth, W. J., Leonowicz, M. E., McCullen, S. B., Hellring, S. D., Beck, J. S., & Schlenker, J. L. (1994) · Chemistry of Materials · doi:10.1021/cm00048a018 · Cited by 542
Iwamoto, M., Furukawa, H., Mine, Y., Uemura, F., Mikuriya, S.-I., & Kagawa, S. (1986) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39860001272 · Cited by 532
Studies on mesoporous materials II. Synthesis mechanism of MCM-41
Chen, C.-Y., Burkett, S. L., Li, H.-X., & Davis, M. E. (1993) · Microporous Materials · doi:10.1016/0927-6513(93)80059-4 · Cited by 454
Beck, J. S., Vartuli, J. C., Kennedy, G. J., Kresge, C. T., Roth, W. J., & Schramm, S. E. (1994) · Chemistry of Materials · doi:10.1021/cm00046a040 · Cited by 392
Model Structures for MCM-41 Materials: A Molecular Dynamics Simulation
Feuston, B. P., & Higgins, J. B. (1994) · The Journal of Physical Chemistry · doi:10.1021/j100067a037 · Cited by 204
Methane Conversion by Oxidative Processes
Wolf, E. E. (1992) · Springer eBooks · doi:10.1007/978-94-015-7449-5 · Cited by 175
Refractive-index-adjustable SiO2-Ta2O5 films for integrated optical circuits
Terui, H., & Kobayashi, M. (1978) · Applied Physics Letters · doi:10.1063/1.89848 · Cited by 58
Cited by
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
Ordered mesoporous materials in catalysis
Taguchi, A., & Schüth, F. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2004.06.030 · Cited by 2,119
Ciesla, U., & Schüth, F. (1999) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(98)00249-2 · Cited by 1,084
Non-siliceous Mesostructured and Mesoporous Materials
Schüth, F. (2001) · Chemistry of Materials · doi:10.1021/cm011030j · Cited by 847
Manganese Oxide Mesoporous Structures: Mixed-Valent Semiconducting Catalysts
Tian, Z.-R., Tong, W., Wang, J.-Y., Duan, N.-G., Krishnan, V. V., & Suib, S. L. (1997) · Science · doi:10.1126/science.276.5314.926 · Cited by 667
Metadata
- Authors
- Antonelli, D. M., & Ying, J. Y.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 8
- Issue
- 4
- Pages
- 874-881
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2074442698
- Cited by
- 279
- References
- 19
- FWCI
- 20.27
- Type
- journal article
- Language
- en
- Open access
- closed
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