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Synthesis and Characterization of Cobalt−Complex Functionalized MCM-41
Abstract
Silanation of the internal pore surface of the mesoporous molecular sieve MCM-41 (40 Å) has yielded ethylenediamine (ED), diethylenetriamine (DET), and ethylenediaminetriacetic acid salt (EDT) functionalized sites. These grafted ligands were used for the preparation of cobalt(II) complexes covalently bound to the MCM-41 support. These materials were characterized by SEM, UV−vis, FTIR, ESR, and cyclic voltammetry as well as elemental analysis. Preliminary studies suggest the formation of a reversible cobalt−oxygen adduct with MCM-41 grafted ED and DET. The nature and reactivity of the MCM-41 bound complexes were found to differ significantly from functionalized amorphous silica.
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Citations
Cited by
A Review: Fundamental Aspects of Silicate Mesoporous Materials
ALOthman, Z. (2012) · Materials · doi:10.3390/ma5122874 · Cited by 2,084
Inclusion Chemistry in Periodic Mesoporous Hosts
Moller, K., & Bein, T. (1998) · Chemistry of Materials · doi:10.1021/cm980243e · Cited by 916
Functionalized micelle-templated silicas (MTS) and their use as catalysts for fine chemicals
Brunel, D. (1999) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(98)00266-2 · Cited by 334
SOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica
Anwander, R. (2001) · Chemistry of Materials · doi:10.1021/cm0111534 · Cited by 320
Metadata
- Authors
- Díaz, J. F., Balkus, K. J., Bedioui, F., Kurshev, V., & Kevan, L.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-01-01
- Volume
- 9
- Issue
- 1
- Pages
- 61-67
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1972900127
- Cited by
- 176
- References
- 0
- FWCI
- 13.40
- Type
- journal article
- Language
- en
- Open access
- closed
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