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Layered Double Hydroxide Stability. 1. Relative Stabilities of Layered Double Hydroxides and Their Simple Counterparts
Abstract
Solutions containing di- and trivalent metal chlorides [M(II) = Mg2+, Zn2+, Co2+, Ni2+, Mn2+; M(III) = Al3+, Fe3+] were titrated with NaOH to yield hydrotalcite-like layered double hydroxides (LDH), [[M(II)]1-x[M(III)]x(OH)2][Cl]x yH2O, by way of M(III) hydroxide/hydrous oxide intermediates. Analysis of the resultant titration curves yields nominal solubility constants for the LDH. The corresponding LDH stabilities are in the order Mg < Mn < Co approximately Ni < Zn for M(II) and Al < Fe for M(III). The stability of LDH relative to the separate metal hydroxides/hydrous oxides is discussed.
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Cited by
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Xu, Z. P., Zhang, J., Adebajo, M. O., Zhang, H., & Zhou, C. (2011) · Applied Clay Science · doi:10.1016/j.clay.2011.02.007 · Cited by 403
Dispersion and Size Control of Layered Double Hydroxide Nanoparticles in Aqueous Solutions
Xu, Z. P., Stevenson, G., Lu, C.-Q., & Lu, G. Q. (. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp062281o · Cited by 323
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Metadata
- Authors
- Boclair, J. W., & Braterman, P. S.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-01-20
- Volume
- 11
- Issue
- 2
- Pages
- 298-302
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2074209371
- Cited by
- 419
- References
- 0
- FWCI
- 4.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Boclair, J. W., & Braterman, P. S. (1999). Layered Double Hydroxide Stability. 1. Relative Stabilities of Layered Double Hydroxides and Their Simple Counterparts. Chemistry of Materials. https://doi.org/10.1021/cm980523u
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